Stannous-modified cyanoborohydride : a new selective reducing agent주석(Ⅱ) 으로 변형된 시안화수소화붕산 : 새로운선택환원제

Cited 0 time in webofscience Cited 0 time in scopus
  • Hit : 524
  • Download : 0
The reducing properties of stannous-modified cyanoborohydride were examined to explore the synthetic utility of the reagent. Stannous-modified cyanoborohydride was prepared by the combination of 1.0 molar equiv of stannous chloride and 2.0 molar equiv of sodium cyanoborohydride. Stannous-modified cyanoborohydride in anhydrous diethyl ether reduced tertiary, allyl, and benzyl halides to corresponding hydrocarbons without attacking primary alkyl, secondary alkyl, and aryl halides. The reagent in diethyl ether reduced aldehydes and ketones to the corresponding alcohols. Furthermore, the reagent in methanol reduced enamines readily to the corresponding amines.
Advisors
Kim, Sung-Gakresearcher김성각researcher
Description
한국과학기술원 : 화학과,
Publisher
한국과학기술원
Issue Date
1985
Identifier
64366/325007 / 000831014
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1985.2, [ iv, 57 p. ]

URI
http://hdl.handle.net/10203/32400
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=64366&flag=dissertation
Appears in Collection
CH-Theses_Master(석사논문)
Files in This Item
There are no files associated with this item.

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0