Stannous-modified cyanoborohydride : a new selective reducing agent주석(Ⅱ) 으로 변형된 시안화수소화붕산 : 새로운선택환원제
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | Kim, Sung-Gak | - |
| dc.contributor.advisor | 김성각 | - |
| dc.contributor.author | Ko, Jae-Suk | - |
| dc.contributor.author | 고재석 | - |
| dc.date.accessioned | 2011-12-13T04:55:57Z | - |
| dc.date.available | 2011-12-13T04:55:57Z | - |
| dc.date.issued | 1985 | - |
| dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=64366&flag=dissertation | - |
| dc.identifier.uri | http://hdl.handle.net/10203/32400 | - |
| dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1985.2, [ iv, 57 p. ] | - |
| dc.description.abstract | The reducing properties of stannous-modified cyanoborohydride were examined to explore the synthetic utility of the reagent. Stannous-modified cyanoborohydride was prepared by the combination of 1.0 molar equiv of stannous chloride and 2.0 molar equiv of sodium cyanoborohydride. Stannous-modified cyanoborohydride in anhydrous diethyl ether reduced tertiary, allyl, and benzyl halides to corresponding hydrocarbons without attacking primary alkyl, secondary alkyl, and aryl halides. The reagent in diethyl ether reduced aldehydes and ketones to the corresponding alcohols. Furthermore, the reagent in methanol reduced enamines readily to the corresponding amines. | eng |
| dc.language | eng | - |
| dc.publisher | 한국과학기술원 | - |
| dc.title | Stannous-modified cyanoborohydride | - |
| dc.title.alternative | 주석(Ⅱ) 으로 변형된 시안화수소화붕산 : 새로운선택환원제 | - |
| dc.type | Thesis(Master) | - |
| dc.identifier.CNRN | 64366/325007 | - |
| dc.description.department | 한국과학기술원 : 화학과, | - |
| dc.identifier.uid | 000831014 | - |
| dc.contributor.localauthor | Kim, Sung-Gak | - |
| dc.contributor.localauthor | 김성각 | - |
| dc.title.subtitle | a new selective reducing agent | - |
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