(The) synthetic utility of 1-fluoro-2,4,6-trunitrobenzene new method for the esterification of carboxylic acids1플루오로 2,4,6 트리니트로 벤젠의 합성에의 응용 유기산의 새로운 에스테르화 반응
A mild, direct transformation of free carboxylic acids with alcohols or thiols into the corresponding esters or thiol esters by the use of l-fluoro-2,4,6-trinitrobenzene as a condensing agent in the presence of 4-dimethylaminopyridine is described. The scope, limitation, and mechanistic insights of this method were studied. The reactions of 1-fluoro-2,4,6-trinitrobenzene with carboxylic acid, alcohols and thiols in the presence of a base were also examined.
- Advisors
- Kim, Sung-Gakresearcher; 김성각researcher
- Description
- 한국과학기술원 : 화학과,
- Publisher
- 한국과학기술원
- Issue Date
- 1981
- Identifier
- 62871/325007 / 000791138
- Language
- eng
- Description
학위논문(석사) - 한국과학기술원 : 화학과, 1981.2, [ iii, 48, [1] p. ]
- Appears in Collection
- CH-Theses_Master(석사논문)
- Files in This Item
- There are no files associated with this item.
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