DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Joosung | ko |
dc.contributor.author | Han, Seungyeob | ko |
dc.contributor.author | Park, Hyejoo | ko |
dc.contributor.author | Kang, Jung-wan | ko |
dc.contributor.author | Kang, Seoktae | ko |
dc.date.accessioned | 2023-01-27T06:01:29Z | - |
dc.date.available | 2023-01-27T06:01:29Z | - |
dc.date.created | 2023-01-16 | - |
dc.date.issued | 2022-11-10 | - |
dc.identifier.citation | The 27th Thailand-Korea Conference on Environmental Engineering (TKCEE) 2022, pp.10 | - |
dc.identifier.uri | http://hdl.handle.net/10203/304711 | - |
dc.description.abstract | During decommission or replacement of nuclear power plants, more than 60% of produced wastes are from surface contaminated or radio-activated concretes. To clean-up these contaminated concrete wastes, acid decommissioning process is widely used to separate radioactive isotopes such as 60Co2+ and 152Eu3+ from crushed concrete particle and then transferred to acidic solutions with plenty amount of Ca2+. To reduce the total amount of radioactive waste, the electrochemical reduction and mineralization process using corrosion-resistive, carbon nanotube based membrane electrode (CR-CME) is investigated in this study for the selective capture of Co2+ from Ca2+-rich acidic leachate. Under the applied voltage of -1.0 V (vs. SCE) and flux of 80 LMH, CR-CME kept its Co2+ removal efficiency higher than 99.7 % in the range of 0.1mM ~ 0.5 mM Co2+ with 0.5 M Ca2+ and pH 2. The maximum Co2+ removal capacity was 69.1 mg/g with 80 LMH of flux until the pores of CR-CME were blocked by the mineralized Co, while CR-CME used with representative electrochemical mineralization condition showed only 27 % and 19.6 mg/g of removal efficiency and capacity, respectively. In addition, the removal capacity of CR-CME was easily restored after the washing of deposited Co by acid such as HNO3. The current results showed that the membrane-type electrode applied electrochemical mineralization system can selectively remove Co2+ from Ca2+-rich acidic leachates generated during decommissioning of radio-activated concrete wastes. | - |
dc.language | English | - |
dc.publisher | KAIST, Chulalongkorn University, Korean Society of Environmental Engineers | - |
dc.title | Corrosion-resistant membrane electrode for the selective capture of Co2+ from Ca2+-rich, acidic wastewater from nuclear decommissioning process | - |
dc.type | Conference | - |
dc.type.rims | CONF | - |
dc.citation.beginningpage | 10 | - |
dc.citation.endingpage | 10 | - |
dc.citation.publicationname | The 27th Thailand-Korea Conference on Environmental Engineering (TKCEE) 2022 | - |
dc.identifier.conferencecountry | KO | - |
dc.identifier.conferencelocation | Seogwipo JS Hotel | - |
dc.contributor.localauthor | Kang, Seoktae | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.