Copper clusters built on bulky amidinate ligands: spin delocalization via superexchange rather than direct metal-metal bonding
Entry into a new class of tetra- and dicopper clusters was assisted by a fine steric tuning of bulky amidinate ligands that provide spin-delocalizing superexchange pathways in class III mixed-valence clusters, the properties of which are best understood without invoking metal-metal bonding.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2005-02
- Language
- English
- Article Type
- Article
- Keywords
DENSITY-FUNCTIONAL THEORY; MOLECULAR-STRUCTURE; REDOX BEHAVIOR; COMPLEXES; POTENTIALS; CHEMISTRY; DESIGN
- Citation
CHEMICAL COMMUNICATIONS, no.8, pp.1043 - 1045
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
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