Copper clusters built on bulky amidinate ligands: spin delocalization via superexchange rather than direct metal-metal bonding

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dc.contributor.authorJiang, Xko
dc.contributor.authorBollinger, JCko
dc.contributor.authorBaik, Mu-Hyunko
dc.contributor.authorLee, Dko
dc.date.accessioned2016-04-12T07:45:15Z-
dc.date.available2016-04-12T07:45:15Z-
dc.date.created2015-09-11-
dc.date.created2015-09-11-
dc.date.issued2005-02-
dc.identifier.citationCHEMICAL COMMUNICATIONS, no.8, pp.1043 - 1045-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/203349-
dc.description.abstractEntry into a new class of tetra- and dicopper clusters was assisted by a fine steric tuning of bulky amidinate ligands that provide spin-delocalizing superexchange pathways in class III mixed-valence clusters, the properties of which are best understood without invoking metal-metal bonding.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectDENSITY-FUNCTIONAL THEORY-
dc.subjectMOLECULAR-STRUCTURE-
dc.subjectREDOX BEHAVIOR-
dc.subjectCOMPLEXES-
dc.subjectPOTENTIALS-
dc.subjectCHEMISTRY-
dc.subjectDESIGN-
dc.titleCopper clusters built on bulky amidinate ligands: spin delocalization via superexchange rather than direct metal-metal bonding-
dc.typeArticle-
dc.identifier.wosid000227609700021-
dc.identifier.scopusid2-s2.0-14944342246-
dc.type.rimsART-
dc.citation.issue8-
dc.citation.beginningpage1043-
dc.citation.endingpage1045-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/b412152j-
dc.contributor.localauthorBaik, Mu-Hyun-
dc.contributor.nonIdAuthorJiang, X-
dc.contributor.nonIdAuthorBollinger, JC-
dc.contributor.nonIdAuthorLee, D-
dc.type.journalArticleArticle-
dc.subject.keywordPlusDENSITY-FUNCTIONAL THEORY-
dc.subject.keywordPlusMOLECULAR-STRUCTURE-
dc.subject.keywordPlusREDOX BEHAVIOR-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusPOTENTIALS-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusDESIGN-
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