Total Synthesis of Ceratopicanol through Tandem Cycloaddition Reaction of a Linear Substrate
Total synthesis of ceratopicanol (1) was achieved with a tandem cycloaddition reaction of allenyl diazo compound 6 via a trimethylenemethane (TMM) diyl intermediate. The TMM diyl mediated [2+3] cycloaddition reaction furnished the consecutive quaternary carbon centers and showed an unusual diastereoselectivity.
- Publisher
- WILEY-V C H VERLAG GMBH
- Issue Date
- 2012-10
- Language
- English
- Article Type
- Article
- Keywords
TRIMETHYLENEMETHANE DIYLS; DIAZO-COMPOUNDS; IN-SITU; (+/-)-CERATOPICANOL; CYCLIZATIONS; TRIQUINANES; SUBSTITUENT; CARBENES; SYSTEM
- Citation
CHEMISTRY-AN ASIAN JOURNAL, v.7, no.10, pp.2450 - 2456
- ISSN
- 1861-4728
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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