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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Total Synthesis of Ceratopicanol through Tandem Cycloaddition Reaction of a Linear Substrate

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dc.contributor.authorLee, Sang-Shinko
dc.contributor.authorKim, Won-Yeobko
dc.contributor.authorLee, Hee-Yoonko
dc.date.accessioned2013-03-12T12:19:50Z-
dc.date.available2013-03-12T12:19:50Z-
dc.date.created2012-11-02-
dc.date.created2012-11-02-
dc.date.issued2012-10-
dc.identifier.citationCHEMISTRY-AN ASIAN JOURNAL, v.7, no.10, pp.2450 - 2456-
dc.identifier.issn1861-4728-
dc.identifier.urihttp://hdl.handle.net/10203/102308-
dc.description.abstractTotal synthesis of ceratopicanol (1) was achieved with a tandem cycloaddition reaction of allenyl diazo compound 6 via a trimethylenemethane (TMM) diyl intermediate. The TMM diyl mediated [2+3] cycloaddition reaction furnished the consecutive quaternary carbon centers and showed an unusual diastereoselectivity.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectTRIMETHYLENEMETHANE DIYLS-
dc.subjectDIAZO-COMPOUNDS-
dc.subjectIN-SITU-
dc.subject(+/-)-CERATOPICANOL-
dc.subjectCYCLIZATIONS-
dc.subjectTRIQUINANES-
dc.subjectSUBSTITUENT-
dc.subjectCARBENES-
dc.subjectSYSTEM-
dc.titleTotal Synthesis of Ceratopicanol through Tandem Cycloaddition Reaction of a Linear Substrate-
dc.typeArticle-
dc.identifier.wosid000308877400039-
dc.identifier.scopusid2-s2.0-84866414140-
dc.type.rimsART-
dc.citation.volume7-
dc.citation.issue10-
dc.citation.beginningpage2450-
dc.citation.endingpage2456-
dc.citation.publicationnameCHEMISTRY-AN ASIAN JOURNAL-
dc.identifier.doi10.1002/asia.201200497-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorLee, Hee-Yoon-
dc.type.journalArticleArticle-
dc.subject.keywordAuthordiradical-
dc.subject.keywordAuthorcycladdition reaction-
dc.subject.keywordAuthorstereoselectivity-
dc.subject.keywordAuthortotal synthesis-
dc.subject.keywordAuthortriquinane-
dc.subject.keywordPlusTRIMETHYLENEMETHANE DIYLS-
dc.subject.keywordPlusDIAZO-COMPOUNDS-
dc.subject.keywordPlusIN-SITU-
dc.subject.keywordPlus(+/-)-CERATOPICANOL-
dc.subject.keywordPlusCYCLIZATIONS-
dc.subject.keywordPlusTRIQUINANES-
dc.subject.keywordPlusSUBSTITUENT-
dc.subject.keywordPlusCARBENES-
dc.subject.keywordPlusSYSTEM-
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