Mesoporous Melamine Resins by Soft Templating of Block-co-Polymer Mesophases

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dc.contributor.authorKailasam, Kamalakannanko
dc.contributor.authorJun, Young-Siko
dc.contributor.authorKatekomol, Phisanko
dc.contributor.authorEpping, Jan Dirkko
dc.contributor.authorHong, Won-Hiko
dc.contributor.authorThomas, Arneko
dc.date.accessioned2013-03-11T12:05:58Z-
dc.date.available2013-03-11T12:05:58Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2010-01-
dc.identifier.citationCHEMISTRY OF MATERIALS, v.22, no.2, pp.428 - 434-
dc.identifier.issn0897-4756-
dc.identifier.urihttp://hdl.handle.net/10203/99270-
dc.description.abstractMesoporous melamine resins have been prepared using hexamethoxymethyl melamine (HMMM) as monomer and block-co-polymer Pluronic F127 as template. At acidic conditions, HMMM condenses into melamine resins, replicating the mesophases formed by the block-co-polymer template. The template can be removed by solvent extraction, yielding mesoporous melamine resins with surface areas of up to 258 m(2)/g and pore diameters of 7.8 nm. At a HMMM/F127 weight ratio of 1:1 an ordered mesoporous melamine resin is observed exhibiting a 2d hexagonal arrangement of cylindrical pores. The simplicity of the synthesis of these mesoporous films allows the large Scale production of the materials, for example, in the form of free-standing films.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectINTRINSIC MICROPOROSITY PIMS-
dc.subjectGRAPHITIC CARBON NITRIDE-
dc.subjectHIERARCHICAL POROSITY-
dc.subjectSORPTION PROPERTIES-
dc.subjectFORMALDEHYDE RESIN-
dc.subjectDIBLOCK COPOLYMER-
dc.subjectORGANIC MATERIALS-
dc.subjectDIOXIDE CAPTURE-
dc.subjectPHENOLIC RESIN-
dc.subjectMETAL NITRIDE-
dc.titleMesoporous Melamine Resins by Soft Templating of Block-co-Polymer Mesophases-
dc.typeArticle-
dc.identifier.wosid000273580700021-
dc.identifier.scopusid2-s2.0-75249095757-
dc.type.rimsART-
dc.citation.volume22-
dc.citation.issue2-
dc.citation.beginningpage428-
dc.citation.endingpage434-
dc.citation.publicationnameCHEMISTRY OF MATERIALS-
dc.identifier.doi10.1021/cm9029903-
dc.contributor.localauthorHong, Won-Hi-
dc.contributor.nonIdAuthorKailasam, Kamalakannan-
dc.contributor.nonIdAuthorKatekomol, Phisan-
dc.contributor.nonIdAuthorEpping, Jan Dirk-
dc.contributor.nonIdAuthorThomas, Arne-
dc.type.journalArticleArticle-
dc.subject.keywordPlusINTRINSIC MICROPOROSITY PIMS-
dc.subject.keywordPlusGRAPHITIC CARBON NITRIDE-
dc.subject.keywordPlusHIERARCHICAL POROSITY-
dc.subject.keywordPlusSORPTION PROPERTIES-
dc.subject.keywordPlusFORMALDEHYDE RESIN-
dc.subject.keywordPlusDIBLOCK COPOLYMER-
dc.subject.keywordPlusORGANIC MATERIALS-
dc.subject.keywordPlusDIOXIDE CAPTURE-
dc.subject.keywordPlusPHENOLIC RESIN-
dc.subject.keywordPlusMETAL NITRIDE-
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