Stereoselectivity in Trimethylenemethane (TMM) Diyl Mediated Cycloaddition Reaction to Angularly Fused Triquinanes
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Yoon, Yeo-Kwon | ko |
| dc.contributor.author | Kang, Taek | ko |
| dc.contributor.author | Lee, Hee-Yoon | ko |
| dc.date.accessioned | 2013-03-11T06:16:48Z | - |
| dc.date.available | 2013-03-11T06:16:48Z | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.issued | 2011-02 | - |
| dc.identifier.citation | CHEMISTRY-AN ASIAN JOURNAL, v.6, no.2, pp.646 - 651 | - |
| dc.identifier.issn | 1861-4728 | - |
| dc.identifier.uri | http://hdl.handle.net/10203/98488 | - |
| dc.description.abstract | A thorough study on the diastereoselectivity in the TMM diyl mediated [2+3] cycloaddition reaction of monosubstituted linear substrates to form angularly fused triquinanes was carried out. Substitution at position 3 provided complete diastereoselectivity, while positions 1 and 4 induced marginal stereoselectivity. Position 2 did not show any influence on the diastereoselectivity. Position 4 turned out to be incompatible with the cycloaddition reaction as the carbene intermediate underwent O-Si bond insertion to form a dihydrofuran ring. | - |
| dc.language | English | - |
| dc.publisher | WILEY-V C H VERLAG GMBH | - |
| dc.subject | KETONES | - |
| dc.title | Stereoselectivity in Trimethylenemethane (TMM) Diyl Mediated Cycloaddition Reaction to Angularly Fused Triquinanes | - |
| dc.type | Article | - |
| dc.identifier.wosid | 000286440600051 | - |
| dc.identifier.scopusid | 2-s2.0-79251518940 | - |
| dc.type.rims | ART | - |
| dc.citation.volume | 6 | - |
| dc.citation.issue | 2 | - |
| dc.citation.beginningpage | 646 | - |
| dc.citation.endingpage | 651 | - |
| dc.citation.publicationname | CHEMISTRY-AN ASIAN JOURNAL | - |
| dc.identifier.doi | 10.1002/asia.201000672 | - |
| dc.contributor.localauthor | Lee, Hee-Yoon | - |
| dc.type.journalArticle | Article | - |
| dc.subject.keywordAuthor | carbenes | - |
| dc.subject.keywordAuthor | cycloaddition | - |
| dc.subject.keywordAuthor | stereoselectivity | - |
| dc.subject.keywordAuthor | trimethylenemethane | - |
| dc.subject.keywordAuthor | triquinane | - |
| dc.subject.keywordPlus | KETONES | - |
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