DC Field | Value | Language |
---|---|---|
dc.contributor.author | Seo, Ji-Youn | ko |
dc.contributor.author | Lee, Seung-Heon | ko |
dc.contributor.author | Jazbinsek, Mojca | ko |
dc.contributor.author | Yun, Ho-Seop | ko |
dc.contributor.author | Kim, Jong-Taek | ko |
dc.contributor.author | Lee, Yoon-Sup | ko |
dc.contributor.author | Baek, In-Hyung | ko |
dc.contributor.author | Rotermund, Fabian Marcel | ko |
dc.contributor.author | Kwon, O-Pil | ko |
dc.date.accessioned | 2013-03-11T02:41:10Z | - |
dc.date.available | 2013-03-11T02:41:10Z | - |
dc.date.created | 2012-03-07 | - |
dc.date.created | 2012-03-07 | - |
dc.date.issued | 2012-01 | - |
dc.identifier.citation | CRYSTAL GROWTH DESIGN, v.12, no.1, pp.313 - 319 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98061 | - |
dc.description.abstract | We investigate new 4-nitophenylhydrazone crystals with thiolated electron donors for nonlinear optical applications. The methylthiolated (SM) electron donor and the biphenyl sulfane (SB) electron donor, which promotes a herringbone packing motif, are incorporated with an acentric nonlinear optical core, nitrophenylhydrazone (NPH), which promotes a lambda-shaped packing motif in the crystalline state. SM-NPH (4-(methylthio)benzaldehyde-4-nitrophenylhydrazone) crystals show head-to-tail hydrogen-bonded chains, which outweigh the usual lambda-shaped packing of the nitrophenylhydrazone group. SB-NPH crystals (4-(phenylthio)benzaldehyde-4-nitrophenylhydrazone) show simultaneous lambda-shaped packing, based on the hydrogen bonds of nitrophenylhydrazone with the nitro electron acceptor group, and the herringbone-shaped packing of biphenyl sulfane groups. Polar SM-NPH chains pack in a centrosymmetric crystal structure, while SB-NPH crystals exhibit a large macroscopic second-order nonlinearity resulting from an acentric molecular ordering of two rotational isomers. In addition, SB-NPH crystals undergo an irreversible phase transition before melting, with the second phase being also acentric with a strong second harmonic generation efficiency. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | CONFIGURATIONALLY LOCKED POLYENE | - |
dc.subject | SINGLE-CRYSTALS | - |
dc.subject | STILBAZOLIUM DERIVATIVES | - |
dc.subject | HYDRAZONE DERIVATIVES | - |
dc.subject | ORGANIC SALTS | - |
dc.subject | GROWTH | - |
dc.subject | 4-NITROPHENYLHYDRAZONES | - |
dc.subject | POLYMORPHS | - |
dc.subject | PACKING | - |
dc.title | New Thiolated Nitrophenylhydrazone Crystals for Nonlinear Optics | - |
dc.type | Article | - |
dc.identifier.wosid | 000298726300043 | - |
dc.identifier.scopusid | 2-s2.0-84855372527 | - |
dc.type.rims | ART | - |
dc.citation.volume | 12 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 313 | - |
dc.citation.endingpage | 319 | - |
dc.citation.publicationname | CRYSTAL GROWTH DESIGN | - |
dc.identifier.doi | 10.1021/cg201115s | - |
dc.contributor.localauthor | Lee, Yoon-Sup | - |
dc.contributor.localauthor | Rotermund, Fabian Marcel | - |
dc.contributor.nonIdAuthor | Seo, Ji-Youn | - |
dc.contributor.nonIdAuthor | Lee, Seung-Heon | - |
dc.contributor.nonIdAuthor | Jazbinsek, Mojca | - |
dc.contributor.nonIdAuthor | Yun, Ho-Seop | - |
dc.contributor.nonIdAuthor | Baek, In-Hyung | - |
dc.contributor.nonIdAuthor | Kwon, O-Pil | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CONFIGURATIONALLY LOCKED POLYENE | - |
dc.subject.keywordPlus | SINGLE-CRYSTALS | - |
dc.subject.keywordPlus | STILBAZOLIUM DERIVATIVES | - |
dc.subject.keywordPlus | HYDRAZONE DERIVATIVES | - |
dc.subject.keywordPlus | ORGANIC SALTS | - |
dc.subject.keywordPlus | GROWTH | - |
dc.subject.keywordPlus | 4-NITROPHENYLHYDRAZONES | - |
dc.subject.keywordPlus | POLYMORPHS | - |
dc.subject.keywordPlus | PACKING | - |
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