DC Field | Value | Language |
---|---|---|
dc.contributor.author | George, Sheby M. | ko |
dc.contributor.author | Yon, Gyu-Hwan | ko |
dc.contributor.author | Park, Bo-Keun | ko |
dc.contributor.author | Lee, Kang-Mun | ko |
dc.contributor.author | Do, Young-Kyu | ko |
dc.contributor.author | Kim, Chang-Gyoun | ko |
dc.contributor.author | Chung, Taek-Mo | ko |
dc.date.accessioned | 2013-03-11T02:05:24Z | - |
dc.date.available | 2013-03-11T02:05:24Z | - |
dc.date.created | 2012-04-18 | - |
dc.date.created | 2012-04-18 | - |
dc.date.issued | 2012-03 | - |
dc.identifier.citation | INORGANICA CHIMICA ACTA, v.383, pp.67 - 71 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98000 | - |
dc.description.abstract | A series of tridentate beta-diketiminate ligands, (2Z, 4E)-4-{[2-(dimethylamino) ethyl] imino}-N-(propan-2-yl) pent-2-en-2-amine ((LH)-H-1), (2Z, 4E)-4-{[3-(dimethylamino) propyl] imino}-N-(tert-butyl) pent-2-en-2-amine ((LH)-H-2), and (2Z, 4E)-4-{[3-(dimethyl-amino) propyl] imino}-N-(propan-2-yl) pent-2-en-2-amine ((LH)-H-3), and their strontium complexes, SrL21 (1), SrL22 (2), and SrL23 (3) were synthesized as potential strontium precursors, by the reaction of Sr[N(SiMe3)(2)](2) and two equivalents of (LH)-H-1, (LH)-H-2, and (LH)-H-3, respectively. Compounds 1-3 were characterized by spectroscopic (IR, MS, H-1 and C-13 NMR), microanalytical methods, and single crystal X-ray diffractometry. The X-ray crystal structure reveals that complex 1 has a monoclinic space group, C2/c. The structure shows the bonding of two beta-diketiminate ligands to the strontium metal through six nitrogen atoms. Additionally, the isopropyl groups on the ligands force 1 to attain a highly distorted octahedron. Thermogravimetric analyses of the compounds 1-3 exhibit a primary mass loss on 130-300 degrees C region. (C) 2011 Elsevier B. V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | ALKALINE-EARTH METALS | - |
dc.subject | SOLUBLE CALCIUM HYDRIDE | - |
dc.subject | SOLID-STATE STRUCTURES | - |
dc.subject | STYRENE POLYMERIZATION | - |
dc.subject | CRYSTALLOGRAPHIC CHARACTERIZATION | - |
dc.subject | INTRAMOLECULAR HYDROAMINATION | - |
dc.subject | CATALYTIC HYDROSILYLATION | - |
dc.subject | BENZYLCALCIUM COMPLEXES | - |
dc.subject | LACTIDE POLYMERIZATION | - |
dc.subject | COORDINATION-COMPLEXES | - |
dc.title | Synthesis and structure of novel strontium complexes of unsymmetrically functionalized beta-diketimine ligands | - |
dc.type | Article | - |
dc.identifier.wosid | 000300623600011 | - |
dc.identifier.scopusid | 2-s2.0-84857237985 | - |
dc.type.rims | ART | - |
dc.citation.volume | 383 | - |
dc.citation.beginningpage | 67 | - |
dc.citation.endingpage | 71 | - |
dc.citation.publicationname | INORGANICA CHIMICA ACTA | - |
dc.identifier.doi | 10.1016/j.ica.2011.10.044 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Do, Young-Kyu | - |
dc.contributor.nonIdAuthor | George, Sheby M. | - |
dc.contributor.nonIdAuthor | Yon, Gyu-Hwan | - |
dc.contributor.nonIdAuthor | Park, Bo-Keun | - |
dc.contributor.nonIdAuthor | Kim, Chang-Gyoun | - |
dc.contributor.nonIdAuthor | Chung, Taek-Mo | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Strontium complexes | - |
dc.subject.keywordAuthor | beta-Diketiminate ligands | - |
dc.subject.keywordAuthor | Tridentate ligands | - |
dc.subject.keywordAuthor | Crystal structure | - |
dc.subject.keywordAuthor | Thermal properties | - |
dc.subject.keywordPlus | ALKALINE-EARTH METALS | - |
dc.subject.keywordPlus | SOLUBLE CALCIUM HYDRIDE | - |
dc.subject.keywordPlus | SOLID-STATE STRUCTURES | - |
dc.subject.keywordPlus | STYRENE POLYMERIZATION | - |
dc.subject.keywordPlus | CRYSTALLOGRAPHIC CHARACTERIZATION | - |
dc.subject.keywordPlus | INTRAMOLECULAR HYDROAMINATION | - |
dc.subject.keywordPlus | CATALYTIC HYDROSILYLATION | - |
dc.subject.keywordPlus | BENZYLCALCIUM COMPLEXES | - |
dc.subject.keywordPlus | LACTIDE POLYMERIZATION | - |
dc.subject.keywordPlus | COORDINATION-COMPLEXES | - |
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