Stereospecific Synthesis of alpha-Substituted syn-alpha,beta-Diamino Acids by the Diaza-Cope Rearrangement
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kim, Hyunwoo | ko |
| dc.contributor.author | Chin, J | ko |
| dc.date.accessioned | 2013-03-09T17:16:15Z | - |
| dc.date.available | 2013-03-09T17:16:15Z | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.created | 2012-02-06 | - |
| dc.date.issued | 2009-11 | - |
| dc.identifier.citation | ORGANIC LETTERS, v.11, no.22, pp.5258 - 5260 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | http://hdl.handle.net/10203/96970 | - |
| dc.description.abstract | Diaza-Cope rearrangement is used to make a variety of alpha-substituted syn-alpha,beta-diamino acids. The rearrangement takes place with complete transfer of stereochemical integrity (>97% de and >98% ee) giving only one of four possible stereoisomers as determined by X-ray crystallography, (1)H NMR, and chiral HPLC. The observed stereospecificity can be explained in terms of DFT computation. This represents the first 1,4-diaza-Cope rearrangement with a ketone. | - |
| dc.language | English | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Stereospecific Synthesis of alpha-Substituted syn-alpha,beta-Diamino Acids by the Diaza-Cope Rearrangement | - |
| dc.type | Article | - |
| dc.identifier.wosid | 000271583000042 | - |
| dc.identifier.scopusid | 2-s2.0-70749103412 | - |
| dc.type.rims | ART | - |
| dc.citation.volume | 11 | - |
| dc.citation.issue | 22 | - |
| dc.citation.beginningpage | 5258 | - |
| dc.citation.endingpage | 5260 | - |
| dc.citation.publicationname | ORGANIC LETTERS | - |
| dc.identifier.doi | 10.1021/ol9021904 | - |
| dc.contributor.localauthor | Kim, Hyunwoo | - |
| dc.contributor.nonIdAuthor | Chin, J | - |
| dc.description.isOpenAccess | N | - |
| dc.type.journalArticle | Article | - |
| dc.subject.keywordPlus | CATALYTIC ASYMMETRIC-SYNTHESIS | - |
| dc.subject.keywordPlus | AMINO-ACIDS | - |
| dc.subject.keywordPlus | MANNICH REACTION | - |
| dc.subject.keywordPlus | MOTHER DIAMINE | - |
| dc.subject.keywordPlus | DERIVATIVES | - |
| dc.subject.keywordPlus | IMINES | - |
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