Redox-induced performance degradation of anode-supported tubular solid oxide fuel cells

Abstract

Redox behavior of a Ni-Y(2)O(3)(-)stabilized ZrO(2) (YSZ) composite anode support and the performance degradation of an anode-supported tubular solid oxide fuel cell (SOFC) were studied under complete oxidation and reduction conditions (degrees of oxidation and reduction = 100%). Materials characterization studies showed that the exposure time in oxidizing and reducing atmospheres played a critical role in the degradation of the porous structures and the physical properties of the anode support. In particular, the redox cycling with an 8 h exposure time resulted in the cracking of YSZ network, leading to significant decay of the mechanical strength. The polarization experiments on the redox-cycled anode-supported tubular cell showed serious performance degradation as a result of the decreases of open-circuit potential and power density. The ac-impedance measurements combined with microstructural observations indicated that the performance degradation resulted mainly from (i) the degradation of anode support, (ii) microcracks across the whole cell, and (iii) interface delamination. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.