DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Woo-Hyun | ko |
dc.contributor.author | Yun, Choamun | ko |
dc.contributor.author | Kim, Young | ko |
dc.contributor.author | Park, Jeong-Ho | ko |
dc.contributor.author | Park, Sun-Won | ko |
dc.contributor.author | Jung, Ki-Taek | ko |
dc.contributor.author | Lee, Yong-Hwa | ko |
dc.contributor.author | Kim, Sae-Heon | ko |
dc.date.accessioned | 2013-03-09T03:13:46Z | - |
dc.date.available | 2013-03-09T03:13:46Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2011-02 | - |
dc.identifier.citation | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.50, no.3, pp.1187 - 1195 | - |
dc.identifier.issn | 0888-5885 | - |
dc.identifier.uri | http://hdl.handle.net/10203/95222 | - |
dc.description.abstract | A mathematical model for a tubular reactor producing epichlorohydrin (ECH) over titanium silicate-1 (TS-1) catalyst is proposed in this work. The Eley-Rideal mechanism is selected to describe the catalytic reaction, and pertinent kinetic parameters are estimated by a genetic algorithm combined with the Levenberg-Marquardt algorithm. The time-varying catalytic activity and effectiveness factor of a commercial TS-1 catalyst pellet are additionally included in the two-dimensional dynamic mass and energy transport model for the packed-bed tubular reactor. In a case study, the optimal length of the tubular reactor is determined by simulations using the developed model to maintain both conversion and selectivity above 96% during 90 days. The proposed model will contribute to effective design of industrial ECH production processes. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | HYDROGEN-PEROXIDE | - |
dc.subject | HEAT-TRANSFER | - |
dc.subject | HYDROXYLATION | - |
dc.subject | EPOXIDATION | - |
dc.subject | SILICALITE | - |
dc.subject | PROPYLENE | - |
dc.subject | OPTIMIZATION | - |
dc.subject | SUBSTANCES | - |
dc.subject | ALGORITHM | - |
dc.title | Modeling of a Tubular Reactor Producing Epichlorohydrin with Consideration of Reaction Kinetics and Deactivation of Titanium Silicate-1 Catalyst | - |
dc.type | Article | - |
dc.identifier.wosid | 000286499800005 | - |
dc.identifier.scopusid | 2-s2.0-79952788722 | - |
dc.type.rims | ART | - |
dc.citation.volume | 50 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 1187 | - |
dc.citation.endingpage | 1195 | - |
dc.citation.publicationname | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | - |
dc.identifier.doi | 10.1021/ie101071m | - |
dc.contributor.localauthor | Park, Sun-Won | - |
dc.contributor.nonIdAuthor | Yun, Choamun | - |
dc.contributor.nonIdAuthor | Kim, Young | - |
dc.contributor.nonIdAuthor | Park, Jeong-Ho | - |
dc.contributor.nonIdAuthor | Jung, Ki-Taek | - |
dc.contributor.nonIdAuthor | Lee, Yong-Hwa | - |
dc.contributor.nonIdAuthor | Kim, Sae-Heon | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | HYDROGEN-PEROXIDE | - |
dc.subject.keywordPlus | HEAT-TRANSFER | - |
dc.subject.keywordPlus | HYDROXYLATION | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | SILICALITE | - |
dc.subject.keywordPlus | PROPYLENE | - |
dc.subject.keywordPlus | OPTIMIZATION | - |
dc.subject.keywordPlus | SUBSTANCES | - |
dc.subject.keywordPlus | ALGORITHM | - |
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