Metal-Enhanced Multiphoton Absorption Polymerization with Gold Nanowires
Metal-enhanced multiphoton absorption polymerization (MEMAP) is studied using gold nanowires with a set of three different photoresists. Photoresists that employ radical and cationic polymerization are investigated. In all cases, MEMAP is strongly correlated with multiphoton-absorption-induced luminescence (MAIL) of the nanowires. Wavelength-dependent studies indicate that the dominant mechanism for MEMAP is not field-enhanced two-photon absorption of the photoinitiator, but rather single-photon excitation of the photoinitiator by the broadband MAIL emission.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2010
- Language
- English
- Article Type
- Article
- Keywords
NEAR-FIELD; 2-PHOTON LUMINESCENCE; NANORODS; PHOTOLUMINESCENCE; PHOTOPOLYMERIZATION; NANOPARTICLES; SPECTROSCOPY; FABRICATION; SURFACES; NOBLE
- Citation
JOURNAL OF PHYSICAL CHEMISTRY C, v.114, no.17, pp.7774 - 7779
- ISSN
- 1932-7447
- Appears in Collection
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