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College of Engineering(공과대학)Dept. of Chemical and Biomolecular Engineering(생명화학공학과)CBE-Journal Papers(저널논문)

Superoxide Ions Entrapped in Water Cages of Ionic Clathrate Hydrates

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dc.contributor.authorCha, Min-Junko
dc.contributor.authorShin, Kyu-Chulko
dc.contributor.authorKwon, Min-Chulko
dc.contributor.authorKoh, Dong-Yeunko
dc.contributor.authorSung, Bo-Ramko
dc.contributor.authorLee, Huenko
dc.date.accessioned2013-03-08T23:09:06Z-
dc.date.available2013-03-08T23:09:06Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2010-03-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.11, pp.3694 - +-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/94607-
dc.description.abstractIn the present work, we first described the stable entrapment of the Superoxide ions in gamma-irradiated (Me(4)NOH + O(2)) clathrate hydrate. Owing to peculiar direct guest-guest ionic interaction, the lattice structure of gamma-irradiated (Me(4)NOH + O(2)) clathrate hydrate shows significant change of lattice contraction behavior even at relatively high temperature (120 K). Such Findings are expected to provide useful information for a better understanding of unrevealed nature (such as icy nanoreactor concept, ice-based functional material synthesis and lattice tuning by specific ionic guests) of clathrate hydrate fields.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectGUEST MOLECULES-
dc.subjectESR-
dc.subjectTRANSITION-
dc.subjectINCLUSION-
dc.subjectELECTRON-
dc.subjectTIO2-
dc.titleSuperoxide Ions Entrapped in Water Cages of Ionic Clathrate Hydrates-
dc.typeArticle-
dc.identifier.wosid000275868700026-
dc.identifier.scopusid2-s2.0-77949797669-
dc.type.rimsART-
dc.citation.volume132-
dc.citation.issue11-
dc.citation.beginningpage3694-
dc.citation.endingpage+-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/ja1004762-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorKoh, Dong-Yeun-
dc.contributor.localauthorLee, Huen-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusGUEST MOLECULES-
dc.subject.keywordPlusESR-
dc.subject.keywordPlusTRANSITION-
dc.subject.keywordPlusINCLUSION-
dc.subject.keywordPlusELECTRON-
dc.subject.keywordPlusTIO2-
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