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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Acetone Cyanohydrin as a Source of HCN in the Cu-Catalyzed Hydrocyanation of alpha-Aryl Diazoacetates

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dc.contributor.authorPark, Eun Juko
dc.contributor.authorLee, Seungeonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2013-03-08T19:40:04Z-
dc.date.available2013-03-08T19:40:04Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2010-04-
dc.identifier.citationJOURNAL OF ORGANIC CHEMISTRY, v.75, no.8, pp.2760 - 2762-
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/10203/94073-
dc.description.abstractA procedure for the Cu-catalyzed hydrocyanation of alpha-aryl diazoesters has been developed using acetone cyanohydrin as a source of hydrogen cyanide (HCN). It was found that the addition of trimethylsilyl cyanide (TMSCN) significantly accelerates the conversion presumably by delivering free cyanide ion in situ, thus producing various types of alpha-aryl cyanoacetates in high yields under mild conditions.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectWEAKLY COORDINATING ANIONS-
dc.subjectH INSERTION REACTIONS-
dc.subjectDIAZO-COMPOUNDS-
dc.subjectENANTIOSELECTIVE SYNTHESIS-
dc.subjectQUATERNARY STEREOCENTERS-
dc.subjectDIAZOCARBONYL COMPOUNDS-
dc.subjectASYMMETRIC CATALYST-
dc.subjectRHODIUM CARBENOIDS-
dc.subjectCOPPER-
dc.subjectDERIVATIVES-
dc.titleAcetone Cyanohydrin as a Source of HCN in the Cu-Catalyzed Hydrocyanation of alpha-Aryl Diazoacetates-
dc.typeArticle-
dc.identifier.wosid000276556600045-
dc.identifier.scopusid2-s2.0-77951003571-
dc.type.rimsART-
dc.citation.volume75-
dc.citation.issue8-
dc.citation.beginningpage2760-
dc.citation.endingpage2762-
dc.citation.publicationnameJOURNAL OF ORGANIC CHEMISTRY-
dc.identifier.doi10.1021/jo100356d-
dc.contributor.localauthorChang, Sukbok-
dc.type.journalArticleArticle-
dc.subject.keywordPlusWEAKLY COORDINATING ANIONS-
dc.subject.keywordPlusH INSERTION REACTIONS-
dc.subject.keywordPlusDIAZO-COMPOUNDS-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusQUATERNARY STEREOCENTERS-
dc.subject.keywordPlusDIAZOCARBONYL COMPOUNDS-
dc.subject.keywordPlusASYMMETRIC CATALYST-
dc.subject.keywordPlusRHODIUM CARBENOIDS-
dc.subject.keywordPlusCOPPER-
dc.subject.keywordPlusDERIVATIVES-
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