Total Synthesis of (-)-13-Acetoxymodhephene and (+)-14-Acetoxymodhephene
Stereoselective epoxidation of [4.3.3]propellane 16 set the stage for the Lewis acid catalyzed stereospecific ring contraction to an oxygenated modhephene structure and eventually led to the total synthesis of (-)-13-acetoxymodhephene and (+)-14-acetoxyrnodhephene. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
- Publisher
- WILEY-V C H VERLAG GMBH
- Issue Date
- 2009-10
- Language
- English
- Article Type
- Article
- Keywords
ENANTIOSELECTIVE SYNTHESIS; ABSOLUTE-CONFIGURATION; OPTICAL RESOLUTION; MODHEPHENE; SESQUITERPENES; ALCOHOLS; REAGENT; KETONES; (+/-)-MODHEPHENE; (-)-MODHEPHENE
- Citation
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, no.29, pp.5028 - 5037
- ISSN
- 1434-193X
- Appears in Collection
- CH-Journal Papers(저널논문)
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