Low-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State

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dc.contributor.authorFan, Jieko
dc.contributor.authorDai, Yihuko
dc.contributor.authorLi, Yunlongko
dc.contributor.authorZheng, Nanfengko
dc.contributor.authorGuo, Junfangko
dc.contributor.authorYan, Xiaoqingko
dc.contributor.authorStucky, Galen D.ko
dc.date.accessioned2013-03-08T18:33:36Z-
dc.date.available2013-03-08T18:33:36Z-
dc.date.created2012-03-12-
dc.date.created2012-03-12-
dc.date.issued2009-11-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.43, pp.15568 - 15568-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/93924-
dc.description.abstractA newly developed mesoporous mixed metal oxide (K-Cu-TiO2) catalyst is capable of highly selective, gas-phase benzyl alcoholbenzaldehyde transformation at excellent yields (>99%) under surprisingly low temperatures (203 degrees C, bp of benzyl alcohol). The tow-temperature reaction conditions and integration of K and Cu(I) components into the TiO2 matrix are of vital importance for the stabilization of an active Cu(I) oxidation state and resultant stable, excellent catalytic performance.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectSOLVENT-FREE OXIDATION-
dc.subjectMOLECULAR-OXYGEN-
dc.subjectCATALYSTS-
dc.subjectGOLD-
dc.subjectALDEHYDES-
dc.subjectGREEN-
dc.titleLow-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State-
dc.typeArticle-
dc.identifier.wosid000271513600001-
dc.identifier.scopusid2-s2.0-70350635640-
dc.type.rimsART-
dc.citation.volume131-
dc.citation.issue43-
dc.citation.beginningpage15568-
dc.citation.endingpage15568-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/ja9032499-
dc.contributor.nonIdAuthorFan, Jie-
dc.contributor.nonIdAuthorDai, Yihu-
dc.contributor.nonIdAuthorLi, Yunlong-
dc.contributor.nonIdAuthorZheng, Nanfeng-
dc.contributor.nonIdAuthorGuo, Junfang-
dc.contributor.nonIdAuthorYan, Xiaoqing-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSOLVENT-FREE OXIDATION-
dc.subject.keywordPlusMOLECULAR-OXYGEN-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusGOLD-
dc.subject.keywordPlusALDEHYDES-
dc.subject.keywordPlusGREEN-
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