Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts
Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2006
- Language
- English
- Article Type
- Article
- Keywords
MESOPOROUS SILICA; PALLADIUM; HYDROGENATION; NANOPARTICLES; HYDROGENOLYSIS; EFFICIENT
- Citation
CHEMICAL COMMUNICATIONS, no.12, pp.1325 - 1327
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
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