DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Yonghoon | ko |
dc.contributor.author | Lee, Sungyul | ko |
dc.contributor.author | Kim, Bongsoo | ko |
dc.date.accessioned | 2013-03-07T18:31:11Z | - |
dc.date.available | 2013-03-07T18:31:11Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008-07 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY A, v.112, no.30, pp.6893 - 6901 | - |
dc.identifier.issn | 1089-5639 | - |
dc.identifier.uri | http://hdl.handle.net/10203/90941 | - |
dc.description.abstract | We have investigated the Rb(2) 475 nm system by resonance enhanced two-photon ionization spectroscopy in a pulsed molecular beam. Strong extra bands accompanying the 2 (1)Pi(u) nu' = 5 - 8 <- X (1)Sigma(+)(g) nu '' = 0 bands were newly observed. Rotational analysis of the main and extra bands reveals that the 2 (1)Pi(u) nu' = 5 - 8 levels are significantly perturbed, mainly by the 3 (3)Sigma(+)(u)(1(u)) state and also by the 2 (3)Pi(u)(1(u)) state. For the major perturber, 3 (3)Sigma(+)(u)(1(u)), the intensity borrowing has been found to be facilitated by the 2 (3)Pi(+)(u)(1(u)) potential energy curve crossing near 21100 cm(-1). For the vibronic-band intensities of the 2 (3)Pi(u)(1(u)) nu' <- X (1)Sigma(+)(g) nu '' = 0 transitions observed in this spectral region, intensity borrowing was most effective when the 2 (3)Pi(u)(1(u)) levels were close to the 3 (3)Sigma(+)(u)(1(u)) levels. A deperturbation fit for the perturbing bands has provided the 2 (1)Pi(u)-3 (3)Sigma(+)(u)(1(u)) coupling constants. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | LASER-INDUCED FLUORESCENCE | - |
dc.subject | FOURIER-TRANSFORM SPECTROSCOPY | - |
dc.subject | PULSED MOLECULAR-BEAM | - |
dc.subject | ELECTRONIC STATES | - |
dc.subject | PREDISSOCIATION | - |
dc.subject | DYNAMICS | - |
dc.subject | RB2 | - |
dc.subject | NM | - |
dc.title | Spin-forbidden transitions in the vicinity of the 2 (1)Pi(u)<- X(1)Sigma(+)(g) band system of Rb(2) | - |
dc.type | Article | - |
dc.identifier.wosid | 000257926900016 | - |
dc.identifier.scopusid | 2-s2.0-49349105607 | - |
dc.type.rims | ART | - |
dc.citation.volume | 112 | - |
dc.citation.issue | 30 | - |
dc.citation.beginningpage | 6893 | - |
dc.citation.endingpage | 6901 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.identifier.doi | 10.1021/jp801560a | - |
dc.contributor.localauthor | Kim, Bongsoo | - |
dc.contributor.nonIdAuthor | Lee, Yonghoon | - |
dc.contributor.nonIdAuthor | Lee, Sungyul | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LASER-INDUCED FLUORESCENCE | - |
dc.subject.keywordPlus | FOURIER-TRANSFORM SPECTROSCOPY | - |
dc.subject.keywordPlus | PULSED MOLECULAR-BEAM | - |
dc.subject.keywordPlus | ELECTRONIC STATES | - |
dc.subject.keywordPlus | PREDISSOCIATION | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordPlus | RB2 | - |
dc.subject.keywordPlus | NM | - |
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