DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, DH | ko |
dc.contributor.author | Koo, JE | ko |
dc.contributor.author | Hong, CS | ko |
dc.contributor.author | Oh, S | ko |
dc.contributor.author | Do, Youngkyu | ko |
dc.date.accessioned | 2013-03-07T17:37:12Z | - |
dc.date.available | 2013-03-07T17:37:12Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2005-06 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.44, no.12, pp.4383 - 4390 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/90800 | - |
dc.description.abstract | The first examples of high-dimensional mixed-valence homometallic cyano-bridged copper complexes were synthesized and characterized: net-structured [Cu(CN)(4){Cu(cyclam)}(1,5)](2n)(H2O)(5n) (1), ladder-type double-chainstructured [Cu(CN)(2){Cu(CN)(2)Cu(cyclam)}],(H2O), (2), layer-structured [{Cu(CN)(2)}(2)Cu(cycalm)](n) (3), and hydrogen-bond-based 2-D [Cu(CN)(3)Cu(cyclam)](n)(CH3OH)(n) (4) (cyclam = 1,4,8,11-tetraazacyclotetradecane). 1 crystallizes in triclinic space group P1 with a = 8.3589(11) angstrom, b = 13.478(2) angstrom, c = 14.828(2) angstrom, alpha = 66.895(2)degrees, beta = 77.916(3)degrees, gamma = 85.939(3)degrees, and Z = 1; 2 crystallizes in triclinic space group P1 with a = 8.2305(12) angstrom, b = 9.8861(15) angstrom, c = 13.219(2) angstrom, alpha = 84.863(3)degrees, beta = 75.744(3)degrees, gamma = 89.818(3)degrees, and Z = 2; 3 crystallizes in monoclinic space group P2(1)/c with a = 6.830(2) angstrom, b = 8.482(2) angstrom, c = 17.306(4) angstrom, beta = 98.144(4)degrees, and Z = 2; 4 crystallizes in triclinic space group P1 with a = 9.470(1) angstrom, b = 10.034(1) angstrom, c = 12.064(1) angstrom, alpha = 67.325(2), beta = 75.593(2), gamma = 70.672(2), and Z = 2. The coordination sphere of Cu-I sites in the complexes shows diverse structures: tetrahedral [CuC4] for 1, tetrahedral [CuC3N] and triangular [CuC2N] for 2, triangular [CuC2N] for 3, and triangular [CuC3] for 4. In particular, 1 constitutes the first example of a structurally characterized system containing a bridging tetrahedral [Cu(CN)4](3-) unit. The diverse structural nature of these complexes is governed by the capping amines and the content of water in the reaction media. The magnetic interactions are negligible in these mixed-valence complexes. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | STATE COORDINATION CHEMISTRY | - |
dc.subject | LADDER CHAIN STRUCTURE | - |
dc.subject | CRYSTAL-STRUCTURE | - |
dc.subject | MAGNETIC-PROPERTIES | - |
dc.subject | BIMETALLIC ASSEMBLIES | - |
dc.subject | STRUCTURAL-CHARACTERIZATION | - |
dc.subject | HYDROTHERMAL SYNTHESIS | - |
dc.subject | METALLASILOXANE CAGE | - |
dc.subject | ORGANOAMINE SYSTEM | - |
dc.subject | LIGAND INFLUENCES | - |
dc.title | Novel examples of high-dimensional mixed-valence copper cyanide complexes | - |
dc.type | Article | - |
dc.identifier.wosid | 000229710600042 | - |
dc.identifier.scopusid | 2-s2.0-20744436343 | - |
dc.type.rims | ART | - |
dc.citation.volume | 44 | - |
dc.citation.issue | 12 | - |
dc.citation.beginningpage | 4383 | - |
dc.citation.endingpage | 4390 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic048267c | - |
dc.contributor.localauthor | Do, Youngkyu | - |
dc.contributor.nonIdAuthor | Kim, DH | - |
dc.contributor.nonIdAuthor | Koo, JE | - |
dc.contributor.nonIdAuthor | Hong, CS | - |
dc.contributor.nonIdAuthor | Oh, S | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | STATE COORDINATION CHEMISTRY | - |
dc.subject.keywordPlus | LADDER CHAIN STRUCTURE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | BIMETALLIC ASSEMBLIES | - |
dc.subject.keywordPlus | STRUCTURAL-CHARACTERIZATION | - |
dc.subject.keywordPlus | HYDROTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | METALLASILOXANE CAGE | - |
dc.subject.keywordPlus | ORGANOAMINE SYSTEM | - |
dc.subject.keywordPlus | LIGAND INFLUENCES | - |
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