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College of Engineering(공과대학)Dept. of Nuclear and Quantum Engineering(원자력및양자공학과)NE-Journal Papers(저널논문)

Epoxidation of olefins by molybdenum(VI) catalysts supported on functional polyimide particulates

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dc.contributor.authorAhn, JHko
dc.contributor.authorKim, JCko
dc.contributor.authorIhm, Son Kiko
dc.contributor.authorOh, CGko
dc.contributor.authorSherrington, DCko
dc.date.accessioned2013-03-07T12:43:27Z-
dc.date.available2013-03-07T12:43:27Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-11-
dc.identifier.citationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.44, no.23, pp.8560 - 8564-
dc.identifier.issn0888-5885-
dc.identifier.urihttp://hdl.handle.net/10203/90200-
dc.description.abstractFunctional polyimides have been prepared in a bead form by nonaqueous suspension polycondensation. A molybdenum(VI) complex was supported on the functional polyimide particulates containing a triazole group and used as a catalyst in the liquid-phase epoxidation of higher olefins with tert-butyl hydroperoxide as the oxygen source. Serious degradation of the polyimide-supported Mo(VI) catalyst does not happen in air until similar to 400 degrees C. The polyimide-supported Mo catalyst was highly active and selective and could be recycled 10 times with no detectable loss of Mo from the support.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectIMIDAZOLE-CONTAINING POLYMERS-
dc.subjectTERT-BUTYL HYDROPEROXIDE-
dc.subjectCYCLOHEXENE-
dc.subjectCOMPLEXES-
dc.subjectMO(VI)-
dc.subjectOXIDATION-
dc.subjectOCT-1-ENE-
dc.titleEpoxidation of olefins by molybdenum(VI) catalysts supported on functional polyimide particulates-
dc.typeArticle-
dc.identifier.wosid000233214000011-
dc.identifier.scopusid2-s2.0-28444450447-
dc.type.rimsART-
dc.citation.volume44-
dc.citation.issue23-
dc.citation.beginningpage8560-
dc.citation.endingpage8564-
dc.citation.publicationnameINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH-
dc.identifier.doi10.1021/ie040287z-
dc.contributor.localauthorIhm, Son Ki-
dc.contributor.nonIdAuthorAhn, JH-
dc.contributor.nonIdAuthorKim, JC-
dc.contributor.nonIdAuthorOh, CG-
dc.contributor.nonIdAuthorSherrington, DC-
dc.type.journalArticleArticle-
dc.subject.keywordPlusIMIDAZOLE-CONTAINING POLYMERS-
dc.subject.keywordPlusTERT-BUTYL HYDROPEROXIDE-
dc.subject.keywordPlusCYCLOHEXENE-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusMO(VI)-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusOCT-1-ENE-
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CBE-Journal Papers(저널논문)
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