Electrooptical and electrochemical properties of an ionic conjugated polymer, poly(2-ethynylpyridinum-N-benzoylsulfonate)

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dc.contributor.authorGal, YSko
dc.contributor.authorJin, SHko
dc.contributor.authorLee, WCko
dc.contributor.authorPark, JWko
dc.contributor.authorLim, KTko
dc.contributor.authorLyoo, WSko
dc.contributor.authorKim, Sang Youlko
dc.date.accessioned2013-03-07T12:40:49Z-
dc.date.available2013-03-07T12:40:49Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2008-09-
dc.identifier.citationRUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, v.82, no.9, pp.1447 - 1450-
dc.identifier.issn0036-0244-
dc.identifier.urihttp://hdl.handle.net/10203/90197-
dc.description.abstractThe electrooptical and electrochemical properties of a self-dopable ionic conjugated polyacetylene, poly(2-ethynylpyridinium-N-benzoylsulfonate) (PEPBS), were studied. The photoluminescence spectra of the polymer showed that the photoluminescence peak was located at 545 nm corresponding to the photon energy of 2.27 eV. The cyclic voltammograms of the polymer exhibited reversible electrochemical behaviors between the doped and undoped peaks. It was found from the dependence of the oxidation current density of the polymer on scan rate that the kinetics of the redox process was diffusion-controlled. The electrical conductivity (sigma) of undoped PEPBS was 5.7 x 10(-9) S/cm.-
dc.languageEnglish-
dc.publisherMAIK NAUKA/INTERPERIODICA/SPRINGER-
dc.subjectSUBSTITUTED ACETYLENES-
dc.subjectMETATHESIS CATALYSTS-
dc.subjectPOLYACETYLENES-
dc.subjectCYCLOPOLYMERIZATION-
dc.subject2-ETHYNYLPYRIDINE-
dc.subjectDERIVATIVES-
dc.subjectBROMIDE)-
dc.subjectMOIETY-
dc.subjectSALTS-
dc.subjectACID-
dc.titleElectrooptical and electrochemical properties of an ionic conjugated polymer, poly(2-ethynylpyridinum-N-benzoylsulfonate)-
dc.typeArticle-
dc.identifier.wosid000258677900006-
dc.identifier.scopusid2-s2.0-50249145132-
dc.type.rimsART-
dc.citation.volume82-
dc.citation.issue9-
dc.citation.beginningpage1447-
dc.citation.endingpage1450-
dc.citation.publicationnameRUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A-
dc.identifier.doi10.1134/S0036024408090069-
dc.contributor.localauthorKim, Sang Youl-
dc.contributor.nonIdAuthorGal, YS-
dc.contributor.nonIdAuthorJin, SH-
dc.contributor.nonIdAuthorLee, WC-
dc.contributor.nonIdAuthorPark, JW-
dc.contributor.nonIdAuthorLim, KT-
dc.contributor.nonIdAuthorLyoo, WS-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSUBSTITUTED ACETYLENES-
dc.subject.keywordPlusMETATHESIS CATALYSTS-
dc.subject.keywordPlusPOLYACETYLENES-
dc.subject.keywordPlusCYCLOPOLYMERIZATION-
dc.subject.keywordPlus2-ETHYNYLPYRIDINE-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusBROMIDE)-
dc.subject.keywordPlusMOIETY-
dc.subject.keywordPlusSALTS-
dc.subject.keywordPlusACID-
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