Substrate-directed stereoselectivity in vicinal diamine-catalyzed synthesis of warfarin
A new mechanism involving a diimine intermediate is proposed for vicinal diamine-catalyzed synthesis of warfarin. Decreasing the NCCN dihedral angle by varying the diamine results in an increase in the enantioselectivity of warfarin synthesis.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2006-11
- Language
- English
- Article Type
- Article
- Citation
ORGANIC LETTERS, v.8, no.23, pp.5239 - 5242
- ISSN
- 1523-7060
- Appears in Collection
- CH-Journal Papers(저널논문)
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