DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Ji-Min | ko |
dc.contributor.author | Park, Eun-Ju | ko |
dc.contributor.author | Cho, Seung-Hwan | ko |
dc.contributor.author | Chang, Suk-Bok | ko |
dc.date.accessioned | 2013-03-07T11:30:25Z | - |
dc.date.available | 2013-03-07T11:30:25Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008-06 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.25, pp.7824 - 7824 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/90080 | - |
dc.description.abstract | A highly efficient protocol for the benzyl or allylic C-H functionalization of simple hydrocarbons has been developed using stoichiometric amounts of N-hydroxyphthalimide and Phl(OAc)(2) in the presence of CuCl catalyst. The reaction was revealed to proceed via a radical pathway, in which phthalimide N-oxyl (PINO) radical plays a dual role, serving as a catalytic hydrogen abstractor from hydrocarbons as well as a stoichiometric reagent to couple with the resultant alkyl radicals. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | MOLECULAR-OXYGEN | - |
dc.subject | AEROBIC OXIDATION | - |
dc.subject | TRANSITION-METAL | - |
dc.subject | CATALYSIS | - |
dc.subject | ACID | - |
dc.subject | RADICALS | - |
dc.subject | ALKYL | - |
dc.subject | CYTOCHROME-P-450 | - |
dc.subject | TEMPERATURE | - |
dc.subject | ACTIVATION | - |
dc.title | Cu-facilitated C-O bond formation using N-hydroxyphthalimide: Efficient and selective functionalization of benzyl and allylic C-H bonds | - |
dc.type | Article | - |
dc.identifier.wosid | 000256962000025 | - |
dc.identifier.scopusid | 2-s2.0-45749083802 | - |
dc.type.rims | ART | - |
dc.citation.volume | 130 | - |
dc.citation.issue | 25 | - |
dc.citation.beginningpage | 7824 | - |
dc.citation.endingpage | 7824 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja8031218 | - |
dc.contributor.localauthor | Chang, Suk-Bok | - |
dc.contributor.nonIdAuthor | Lee, Ji-Min | - |
dc.contributor.nonIdAuthor | Park, Eun-Ju | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MOLECULAR-OXYGEN | - |
dc.subject.keywordPlus | AEROBIC OXIDATION | - |
dc.subject.keywordPlus | TRANSITION-METAL | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | RADICALS | - |
dc.subject.keywordPlus | ALKYL | - |
dc.subject.keywordPlus | CYTOCHROME-P-450 | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | ACTIVATION | - |
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