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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Anionic reactions of N-(trans-2,3-diphenylaziridin-1-yl)imines and their use as 1,1-dipoles in anionic cyclizations

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dc.contributor.authorHwang, JIko
dc.contributor.authorHong, YTko
dc.contributor.authorKim, Sung Gakko
dc.date.accessioned2013-03-07T10:50:28Z-
dc.date.available2013-03-07T10:50:28Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-10-
dc.identifier.citationADVANCED SYNTHESIS & CATALYSIS, v.347, no.11-13, pp.1513 - 1516-
dc.identifier.issn1615-4150-
dc.identifier.urihttp://hdl.handle.net/10203/89997-
dc.description.abstractReaction of N-(trans-2,3-diphenylaziridin-1-yl)imines with alkyllithiums and organocuprates afforded the desired addition products after consecutive fragmentations along with liberation of stilbene and nitrogen gas, while the reaction of N-(2-phenylaziridin-1-yl)imines under similar conditions gave an anomalous by-product. Anionic cyclizations of N(trans-2,3-diphenylaziridin-1-yl)imines using unactivated alkenes and alkynes as acceptors proceeded smoothly, yielding cyclized products in good yields.-
dc.languageEnglish-
dc.publisherWiley-Blackwell-
dc.subjectN-AZIRIDINYL IMINES-
dc.subjectBOND FORMATION APPROACH-
dc.subjectRADICAL CYCLIZATION-
dc.subjectALDEHYDE TOSYLHYDRAZONES-
dc.subjectEFFICIENT SYNTHESIS-
dc.subjectLITHIUM REAGENTS-
dc.subjectALKYLLITHIUMS-
dc.subjectGENERATION-
dc.subjectOLIGOMERIZATION-
dc.subjectALKYLATION-
dc.titleAnionic reactions of N-(trans-2,3-diphenylaziridin-1-yl)imines and their use as 1,1-dipoles in anionic cyclizations-
dc.typeArticle-
dc.identifier.wosid000233124500009-
dc.identifier.scopusid2-s2.0-27544453399-
dc.type.rimsART-
dc.citation.volume347-
dc.citation.issue11-13-
dc.citation.beginningpage1513-
dc.citation.endingpage1516-
dc.citation.publicationnameADVANCED SYNTHESIS & CATALYSIS-
dc.identifier.doi10.1002/adsc.200505110-
dc.contributor.localauthorKim, Sung Gak-
dc.contributor.nonIdAuthorHwang, JI-
dc.contributor.nonIdAuthorHong, YT-
dc.type.journalArticleArticle-
dc.subject.keywordAuthoralkyllithiums-
dc.subject.keywordAuthoranionic cyclizations-
dc.subject.keywordAuthoraziridines-
dc.subject.keywordAuthor1,1-dipoles-
dc.subject.keywordAuthorhydrazones-
dc.subject.keywordAuthorimines-
dc.subject.keywordPlusN-AZIRIDINYL IMINES-
dc.subject.keywordPlusBOND FORMATION APPROACH-
dc.subject.keywordPlusRADICAL CYCLIZATION-
dc.subject.keywordPlusALDEHYDE TOSYLHYDRAZONES-
dc.subject.keywordPlusEFFICIENT SYNTHESIS-
dc.subject.keywordPlusLITHIUM REAGENTS-
dc.subject.keywordPlusALKYLLITHIUMS-
dc.subject.keywordPlusGENERATION-
dc.subject.keywordPlusOLIGOMERIZATION-
dc.subject.keywordPlusALKYLATION-
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