Triquinanes from linear ketones via trimethylenemethane diyls
Linear compounds containing a ketone and diene functional groups reacted with the anion of TMS-diazomethane to produce alkylidene carbenes that underwent intramolecular cyclopropanation followed by the formation of trimethylenemethane diyls which underwent [2+3] cycloaddition reaction to produce linearly fused triquinanes. (c) 2006 Elsevier Ltd. All rights reserved.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 2007-02
- Language
- English
- Article Type
- Article
- Keywords
ALKYLIDENE CARBENES; ORGANIC-SYNTHESIS; OLEFINS
- Citation
TETRAHEDRON LETTERS, v.48, no.8, pp.1407 - 1410
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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