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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Synthesis of Condensed Pyrroloindoles via Pd-Catalyzed Intramolecular C-H Bond Functionalization of Pyrroles

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dc.contributor.authorHwang, Seung-Junko
dc.contributor.authorCho, Seung-Hwanko
dc.contributor.authorChang, Suk-Bokko
dc.date.accessioned2013-03-06T22:07:49Z-
dc.date.available2013-03-06T22:07:49Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2008-12-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.48, pp.16158 - 16158-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/88633-
dc.description.abstractA new strategy for the synthesis of condensed hetero- or carbocycles such as pyrroloindoles or fluorenes has been developed that involves the Pd-catalyzed cyclization of readily available N-(2-halobenzyl)pyrroles or their phenyl derivatives. The reaction is proposed to proceed via oxidative addition of benzylic halides to Pd(0) followed by base-assisted C-H bond activation. A broad range of condensed cyclic products could be obtained in good to excellent yields under mild conditions.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectN-FUSED HETEROCYCLES-
dc.subjectDIRECT ARYLATION-
dc.subjectARYL CHLORIDES-
dc.subjectACTIVATION-
dc.subjectINDOLES-
dc.subjectREGIOSELECTIVITY-
dc.subjectHYDROARYLATION-
dc.subjectALKENYLATION-
dc.subjectDERIVATIVES-
dc.subjectMECHANISM-
dc.titleSynthesis of Condensed Pyrroloindoles via Pd-Catalyzed Intramolecular C-H Bond Functionalization of Pyrroles-
dc.typeArticle-
dc.identifier.wosid000263319800017-
dc.identifier.scopusid2-s2.0-57149107584-
dc.type.rimsART-
dc.citation.volume130-
dc.citation.issue48-
dc.citation.beginningpage16158-
dc.citation.endingpage16158-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/ja806897h-
dc.contributor.localauthorChang, Suk-Bok-
dc.contributor.nonIdAuthorHwang, Seung-Jun-
dc.type.journalArticleArticle-
dc.subject.keywordPlusN-FUSED HETEROCYCLES-
dc.subject.keywordPlusDIRECT ARYLATION-
dc.subject.keywordPlusARYL CHLORIDES-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordPlusREGIOSELECTIVITY-
dc.subject.keywordPlusHYDROARYLATION-
dc.subject.keywordPlusALKENYLATION-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusMECHANISM-
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