DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung J.H. | ko |
dc.contributor.author | Rim J.A. | ko |
dc.contributor.author | Cho E.J. | ko |
dc.contributor.author | Lee S.J. | ko |
dc.contributor.author | Jeong I.Y. | ko |
dc.contributor.author | Kameda N. | ko |
dc.contributor.author | Masuda M. | ko |
dc.contributor.author | Shimizu T. | ko |
dc.date.accessioned | 2013-03-06T18:53:47Z | - |
dc.date.available | 2013-03-06T18:53:47Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | TETRAHEDRON, v.63, no.31, pp.7449 - 7456 | - |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/10203/88033 | - |
dc.description.abstract | Asymmetric bolaamphiphilic sugar-based hydrogelators (1-3) were synthesized and their gelation ability with and without alkylammonium ions was investigated by CD, TEM, FTIR and NMR. These compounds acted as versatile gelators for organic solvents and water. The xerogels 1-3 obtained from water showed well-developed structures of fibrils with diameters of 10-38 nm and length of several hundred micrometers. Particularly, the gelation ability of crown-appended gelator 1 was drastically enhanced by addition of alkylammonium ions 4 and 5, suggesting that the bridging effect of alkyldiammonium ions could be the primary driving-force for the stabilization due to the intermolecular hydrogen bonding and electrostatic interactions. The present result is a rare case of a hydrogel being stabilized by a host-guest interaction. In addition, the hydrogel 1 with AgNO3 and KClO4 induced the formation of nanotubular and vesicular structures of silica by sol-gel polymerization of TEOS, respectively. These results indicate that hydrogel 1 acted as a template to produce inorganic nanomaterials. (c) 2007 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | ELECTRON-MICROSCOPIC OBSERVATION | - |
dc.subject | MOLECULAR-WEIGHT HYDROGELATORS | - |
dc.subject | ORGANIC-SOLVENTS | - |
dc.subject | REMARKABLE DIVERSITY | - |
dc.subject | CHOLESTEROL-STILBENE | - |
dc.subject | ORGANOGEL FORMATION | - |
dc.subject | GELATION ABILITY | - |
dc.subject | BIS-UREAS | - |
dc.subject | GELATORS | - |
dc.subject | DERIVATIVES | - |
dc.title | Stabilization of an asymmetric bolaamphiphilic sugar-based crown ether hydrogel by hydrogen bonding interaction and its sol-gel transcription | - |
dc.type | Article | - |
dc.identifier.wosid | 000252082400018 | - |
dc.identifier.scopusid | 2-s2.0-34250652091 | - |
dc.type.rims | ART | - |
dc.citation.volume | 63 | - |
dc.citation.issue | 31 | - |
dc.citation.beginningpage | 7449 | - |
dc.citation.endingpage | 7456 | - |
dc.citation.publicationname | TETRAHEDRON | - |
dc.identifier.doi | 10.1016/j.tet.2007.02.068 | - |
dc.contributor.nonIdAuthor | Jung J.H. | - |
dc.contributor.nonIdAuthor | Rim J.A. | - |
dc.contributor.nonIdAuthor | Lee S.J. | - |
dc.contributor.nonIdAuthor | Jeong I.Y. | - |
dc.contributor.nonIdAuthor | Kameda N. | - |
dc.contributor.nonIdAuthor | Masuda M. | - |
dc.contributor.nonIdAuthor | Shimizu T. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | bolaamphiphiles | - |
dc.subject.keywordAuthor | host-guest chemistry | - |
dc.subject.keywordAuthor | hydrogel | - |
dc.subject.keywordAuthor | self-assembly | - |
dc.subject.keywordAuthor | sol-gel transcription | - |
dc.subject.keywordPlus | ELECTRON-MICROSCOPIC OBSERVATION | - |
dc.subject.keywordPlus | MOLECULAR-WEIGHT HYDROGELATORS | - |
dc.subject.keywordPlus | ORGANIC-SOLVENTS | - |
dc.subject.keywordPlus | REMARKABLE DIVERSITY | - |
dc.subject.keywordPlus | CHOLESTEROL-STILBENE | - |
dc.subject.keywordPlus | ORGANOGEL FORMATION | - |
dc.subject.keywordPlus | GELATION ABILITY | - |
dc.subject.keywordPlus | BIS-UREAS | - |
dc.subject.keywordPlus | GELATORS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
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