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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Halide ions as a highly efficient promoter in the Ru-catalyzed hydroesterification of alkenes and alkynes

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dc.contributor.authorPark, Eun Juko
dc.contributor.authorLee, Ji Minko
dc.contributor.authorHan, Hoonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2013-03-06T18:10:46Z-
dc.date.available2013-03-06T18:10:46Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2006-09-
dc.identifier.citationORGANIC LETTERS, v.8, no.19, pp.4355 - 4358-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/87901-
dc.description.abstractThe presence of catalytic amounts of halide salts was found to enhance dramatically the reaction efficiency in the Ru-catalyzed hydroesterification of alkenes and alkynes using a chelating 2-pyridylmethyl formate by lowering the reaction temperature. On the basis of IR and NMR studies, the halide effect on the reaction is mainly attributed to the facile dissociation of the trirutheniumcarbonyl precursor into the presumed active metal species. With this milder condition, the substrate scope has been significantly broadened.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectCARBON-MONOXIDE-
dc.subjectINTRAMOLECULAR HYDROACYLATION-
dc.subjectHOMOGENEOUS HYDROGENATION-
dc.subjectRUTHENIUM CATALYSTS-
dc.subjectIODIDE PROMOTERS-
dc.subjectTERMINAL ALKYNES-
dc.subjectMETHYL FORMATE-
dc.subjectCOMPLEXES-
dc.subjectRHODIUM-
dc.subjectHYDROAMINATION-
dc.titleHalide ions as a highly efficient promoter in the Ru-catalyzed hydroesterification of alkenes and alkynes-
dc.typeArticle-
dc.identifier.wosid000240339700046-
dc.identifier.scopusid2-s2.0-33749003163-
dc.type.rimsART-
dc.citation.volume8-
dc.citation.issue19-
dc.citation.beginningpage4355-
dc.citation.endingpage4358-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol061753e-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorPark, Eun Ju-
dc.contributor.nonIdAuthorLee, Ji Min-
dc.contributor.nonIdAuthorHan, Hoon-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCARBON-MONOXIDE-
dc.subject.keywordPlusINTRAMOLECULAR HYDROACYLATION-
dc.subject.keywordPlusHOMOGENEOUS HYDROGENATION-
dc.subject.keywordPlusRUTHENIUM CATALYSTS-
dc.subject.keywordPlusIODIDE PROMOTERS-
dc.subject.keywordPlusTERMINAL ALKYNES-
dc.subject.keywordPlusMETHYL FORMATE-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusRHODIUM-
dc.subject.keywordPlusHYDROAMINATION-
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CH-Journal Papers(저널논문)
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