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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Reactivity of Bromodilithiosilane to Napthalene and Anthracene

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dc.contributor.authorLim, Young Mookko
dc.contributor.authorLee, Myong Euyko
dc.contributor.authorLee, Junseongko
dc.contributor.authorDo, Youngkyuko
dc.date.accessioned2013-03-06T16:12:24Z-
dc.date.available2013-03-06T16:12:24Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2008-12-
dc.identifier.citationORGANOMETALLICS, v.27, no.23, pp.6375 - 6378-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10203/87549-
dc.description.abstractBromodilithiosilane, 1, reacted with naphthalene at 110 degrees C to give the silacyclopropane derivative 2, which reacted with MeOH(D), Mel. and Me(3)SiCl to yield 3, 4, and 5 in 84%, 82%, and 85% yields, respectively, 1 also reacted with anthracene at -30 degrees C to give the lithio-silanorbornadiene derivatives, which were trapped by 1-PrOH to yield 6 and 7 as colorless crystals in 27% and 54%. These results show an important synthetic application of 1,1-dilithiosilane bearing a halogen atom, which differs from those of known 1,1-dilithiosilanes.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectSILOLE DIANIONS-
dc.subjectAROMATIC-COMPOUNDS-
dc.subject1ST EXAMPLES-
dc.subjectSILICON-
dc.subjectANIONS-
dc.subject1,1-DILITHIOSILANE-
dc.subjectDERIVATIVES-
dc.subjectSILYLENE-
dc.subjectORGANODILITHIOSILANE-
dc.subjectGENERATION-
dc.titleReactivity of Bromodilithiosilane to Napthalene and Anthracene-
dc.typeArticle-
dc.identifier.wosid000261142000043-
dc.identifier.scopusid2-s2.0-57849084013-
dc.type.rimsART-
dc.citation.volume27-
dc.citation.issue23-
dc.citation.beginningpage6375-
dc.citation.endingpage6378-
dc.citation.publicationnameORGANOMETALLICS-
dc.identifier.doi10.1021/om800596t-
dc.contributor.localauthorDo, Youngkyu-
dc.contributor.nonIdAuthorLim, Young Mook-
dc.contributor.nonIdAuthorLee, Myong Euy-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSILOLE DIANIONS-
dc.subject.keywordPlusAROMATIC-COMPOUNDS-
dc.subject.keywordPlus1ST EXAMPLES-
dc.subject.keywordPlusSILICON-
dc.subject.keywordPlusANIONS-
dc.subject.keywordPlus1,1-DILITHIOSILANE-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusSILYLENE-
dc.subject.keywordPlusORGANODILITHIOSILANE-
dc.subject.keywordPlusGENERATION-
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