Magnetic properties of monodisperse NiHx nanopairticles and comparison to those of monodisperse Ni nanoparticles

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We produced, for the first time, monodisperse NiHx nanoparticles with particle diameters of 7.0 nm and investigated their magnetic properties. We also produced monodisperse Ni nanoparticles with nearly the same particle diameters as those of NiHx nanoparticles as a comparison. The magnetic properties of NiHx nanoparticles were quite different from those of Ni nanoparticles. We observed two compositional phases in NiHx nanoparticles, similar to bulk material: one is the nearly pure Ni phase with the blocking temperature (TB) of 11 K and the other is the hydride phase. We observed T-B of 40 K in Ni nanoparticles.
Publisher
AMER CHEMICAL SOC
Issue Date
2005-06
Language
English
Article Type
Article
Keywords

BAND-STRUCTURE CALCULATIONS; NICKEL-HYDRIDE BATTERIES; HYDROGEN; CLUSTERS; SUSCEPTIBILITY; FERROMAGNETISM; DISAPPEARANCE; MECHANISM; RHODIUM

Citation

JOURNAL OF PHYSICAL CHEMISTRY B, v.109, no.25, pp.12257 - 12260

ISSN
1520-6106
DOI
10.1021/jp050489o
URI
http://hdl.handle.net/10203/87203
Appears in Collection
CH-Journal Papers(저널논문)
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