A molecular pinwheel multicopper(I) cluster, [LS-)(6)Cu-13(I)(S2-)(2)](3+) with mu(4)-sulfido, mu(3)-thiolato and nitrogen ligands

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dc.contributor.authorLee, Yunhoko
dc.contributor.authorSarjeant, AANko
dc.contributor.authorKarlin, KDko
dc.date.accessioned2013-03-06T09:55:47Z-
dc.date.available2013-03-06T09:55:47Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2006-02-
dc.identifier.citationCHEMICAL COMMUNICATIONS, no.6, pp.621 - 623-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/86616-
dc.description.abstractA copper(I) complex with new N2S thiol ligand transforms to a multicopper(I) cluster, [(LS-)(6)Cu-13(I)(S2-)(2)](3+) (1); its X-ray structure exhibiting mu(4)-sulfido and mu(3)-thiolato coordination is presented and compared to other cuprous thiolato/sulfido clusters including that observed in the copper enzyme nitrous oxide reductase.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectC-S BOND-
dc.subjectCUPROUS-THIOLATE CLUSTERS-
dc.subjectX-RAY-STRUCTURE-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectCOPPER CLUSTER-
dc.subjectSTRUCTURAL CHARACTERIZATIONS-
dc.subjectCOMPLEXES-
dc.subjectCHEMISTRY-
dc.subjectCLEAVAGE-
dc.subjectSULFUR-
dc.titleA molecular pinwheel multicopper(I) cluster, [LS-)(6)Cu-13(I)(S2-)(2)](3+) with mu(4)-sulfido, mu(3)-thiolato and nitrogen ligands-
dc.typeArticle-
dc.identifier.wosid000235453100015-
dc.identifier.scopusid2-s2.0-33646062874-
dc.type.rimsART-
dc.citation.issue6-
dc.citation.beginningpage621-
dc.citation.endingpage623-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/b513768c-
dc.contributor.localauthorLee, Yunho-
dc.contributor.nonIdAuthorSarjeant, AAN-
dc.contributor.nonIdAuthorKarlin, KD-
dc.type.journalArticleArticle-
dc.subject.keywordPlusC-S BOND-
dc.subject.keywordPlusCUPROUS-THIOLATE CLUSTERS-
dc.subject.keywordPlusX-RAY-STRUCTURE-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusCOPPER CLUSTER-
dc.subject.keywordPlusSTRUCTURAL CHARACTERIZATIONS-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusCLEAVAGE-
dc.subject.keywordPlusSULFUR-
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