Synthesis of polyamide dendrons bearing pyridine groups as multiple hydrogen bonding parts on the periphery

Cited 3 time in webofscience Cited 3 time in scopus
  • Hit : 307
  • Download : 0
Aromatic polyamide dendrons (G0-G2) having amino groups on the periphery were prepared by divergent method. Reaction of GO aromatic polyamide dendron with isonicotinoyl chloride hydrochloride gave polyamide dendron (G0-2Py) bearing two pyridine groups. The structures of polyamide dendrons were confirmed by IR, H-1, C-13 NMR, MALDI-TOF mass spectroscopy. A hydrogen-bonded G0-2Py/poly(acrylic acid) (PAA) 1/2 complex was prepared by mixing G0-2Py with PAA in methanol, followed by removing the solvent. IR spectrum of G0-2Py/PAA 1/2 complex showed characteristic absorptions at 2550 and 1950cm(-1) due to hydrogen bonding. A glass transition temperature (T-g) of G0-2Py/PAA 1/2 complex was observed at 121 degreesC by DSC measurement, whereas T(g)s of G0-2Py (137degreesC) and PAA (87degreesC) disappeared. T-g of the G0-2Py/PAA complex was dependent on the molar ratio ([Donor]/ [Acceptor]). Maximum T-g at 121 degreesC was observed at a ratio of 1.
Publisher
SOC POLYMER SCIENCE JAPAN
Issue Date
2004
Language
English
Article Type
Article
Keywords

DOT-MELAMINE LATTICE; STARBURST DENDRIMERS; DNA; EPR

Citation

POLYMER JOURNAL, v.36, no.7, pp.513 - 518

ISSN
0032-3896
DOI
10.1295/polymj.36.513
URI
http://hdl.handle.net/10203/83555
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 3 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0