DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yong Hae | ko |
dc.contributor.author | s. m. kim | ko |
dc.contributor.author | s. w. youn | ko |
dc.date.accessioned | 2013-03-04T12:06:17Z | - |
dc.date.available | 2013-03-04T12:06:17Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2001-02 | - |
dc.identifier.citation | PURE AND APPLIED CHEMISTRY, v.73, no.2, pp.283 - 286 | - |
dc.identifier.issn | 0033-4545 | - |
dc.identifier.uri | http://hdl.handle.net/10203/82591 | - |
dc.description.abstract | Diels-Alder cycloadditions of S-indoline chiral acrylamides with cyclopentadiene in the presence of Lewis acids proceed with high diastereofacial selectivity, giving either endo-R or endo-S products depending on Lewis acid and the structures of chiral dienophiles. Diastereo- and enantioselective pinacol coupling reactions of chiral alpha -ketoamides mediated by samarium diiodide afforded extremely high diastereoselectivities. Enantiopure (S,S)- or (R,R)-2,3-dialkyltartaric acid and derivatives can be synthesized. Furthermore, it was demonstrated that alpha,beta -unsaturated amides coupled with SmI2 to dimerized products containing two chiral carbons which were first obtained as the adjacent chiral carbons. | - |
dc.language | English | - |
dc.publisher | Int Union Pure Applied Chemistry | - |
dc.subject | DIELS-ALDER REACTIONS | - |
dc.subject | CHIRAL ACRYLAMIDES | - |
dc.subject | ACID | - |
dc.title | Asymmetric Synthesis by Stereocontrol | - |
dc.type | Article | - |
dc.identifier.wosid | 000168691000017 | - |
dc.identifier.scopusid | 2-s2.0-0035743167 | - |
dc.type.rims | ART | - |
dc.citation.volume | 73 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 283 | - |
dc.citation.endingpage | 286 | - |
dc.citation.publicationname | PURE AND APPLIED CHEMISTRY | - |
dc.contributor.nonIdAuthor | s. m. kim | - |
dc.contributor.nonIdAuthor | s. w. youn | - |
dc.type.journalArticle | Article; Proceedings Paper | - |
dc.subject.keywordPlus | DIELS-ALDER REACTIONS | - |
dc.subject.keywordPlus | CHIRAL ACRYLAMIDES | - |
dc.subject.keywordPlus | ACID | - |
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