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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A facile synthetic route to (+)-allosedamine via hydrolytic kinetic resolution and olefin metathesis

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dc.contributor.authorKang, Bko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2013-03-04T08:33:02Z-
dc.date.available2013-03-04T08:33:02Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2004-08-
dc.identifier.citationTETRAHEDRON, v.60, no.34, pp.7353 - 7359-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10203/82183-
dc.description.abstractA concise synthesis of (+)-allosedamine has been achieved using cobalt-catalyzed hydrolytic kinetic resolution (HKR) and ruthenium-catalyzed ring closing metathesis (RCM) as two key steps, in which HKR was used to introduce both stereogenic centers in the natural compound with a high degree of diastereomeric ratio and cyclization was carried out with the well developed RCM procedure. (C) 2004 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectRING-CLOSING METATHESIS-
dc.subjectRUTHENIUM BY-PRODUCTS-
dc.subjectASYMMETRIC-SYNTHESIS-
dc.subjectCROSS-METATHESIS-
dc.subjectPIPERIDINE ALKALOIDS-
dc.subjectMITSUNOBU REACTION-
dc.subjectTERMINAL EPOXIDES-
dc.subjectOPENING REACTIONS-
dc.subjectCONVENIENT METHOD-
dc.subjectTANDEM CATALYSIS-
dc.titleA facile synthetic route to (+)-allosedamine via hydrolytic kinetic resolution and olefin metathesis-
dc.typeArticle-
dc.identifier.wosid000223090800026-
dc.identifier.scopusid2-s2.0-3342913784-
dc.type.rimsART-
dc.citation.volume60-
dc.citation.issue34-
dc.citation.beginningpage7353-
dc.citation.endingpage7359-
dc.citation.publicationnameTETRAHEDRON-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorKang, B-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorallosedamine-
dc.subject.keywordAuthortotal synthesis-
dc.subject.keywordAuthorhydrolytic kinetic resolution-
dc.subject.keywordAuthorring-closing metathesis-
dc.subject.keywordPlusRING-CLOSING METATHESIS-
dc.subject.keywordPlusRUTHENIUM BY-PRODUCTS-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlusCROSS-METATHESIS-
dc.subject.keywordPlusPIPERIDINE ALKALOIDS-
dc.subject.keywordPlusMITSUNOBU REACTION-
dc.subject.keywordPlusTERMINAL EPOXIDES-
dc.subject.keywordPlusOPENING REACTIONS-
dc.subject.keywordPlusCONVENIENT METHOD-
dc.subject.keywordPlusTANDEM CATALYSIS-
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CH-Journal Papers(저널논문)
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