Highly efficient iridium-catalyzed oxidation of organosilanes to silanols
Hydrolytic oxidation of organosilanes to the corresponding silanols can be performed highly efficiently with a catalyst system of [IrCl(C8H12)](2) under essentially neutral and mild conditions, and various types of silanols are produced in good to excellent yields.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2004-03
- Language
- English
- Article Type
- Article
- Keywords
ASYMMETRIC SILICON; RHODIUM COMPLEX; ALKENYLSILANOLS; STEREOCHEMISTRY; PALLADIUM; 2-(2-HYDROXYETHYL)HOMOALLENYLSILANES; ALPHA,BETA-ENONES; SUBSTITUTION; CONVERSION; INSERTION
- Citation
JOURNAL OF ORGANIC CHEMISTRY, v.69, no.5, pp.1741 - 1743
- ISSN
- 0022-3263
- Appears in Collection
- CH-Journal Papers(저널논문)
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