DC Field | Value | Language |
---|---|---|
dc.contributor.author | Horvat, SM | ko |
dc.contributor.author | Kim, Sung Gak | ko |
dc.contributor.author | Schiesser, CH | ko |
dc.date.accessioned | 2013-03-04T01:01:14Z | - |
dc.date.available | 2013-03-04T01:01:14Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2003-05 | - |
dc.identifier.citation | CHEMICAL COMMUNICATIONS, pp.1182 - 1183 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10203/81183 | - |
dc.description.abstract | Reaction of the optically active silanes, ((S-Si)-(-)- 6), formed by treatment of racemic 2-methylenecycloheptanone oxide with LDA followed by ( R)-(+)-chloromethyl(1-naphthyl)phenylsilane, with tributyltin hydride under standard radical conditions affords (2R/2S)-[(S)-(methyl(1-naphthyl)phenylsilyloxy) methyl] cycloheptanone, ( SSi)-( 2)- 7, providing strong evidence that homolytic 1,5-transfers of organosilicon groups from enoxy oxygen to alkoxy oxygen proceed with retention of configuration, most likely through a frontside attack mechanism rather than via a hypervalent intermediate. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | ATOM-TRANSFER | - |
dc.subject | AB-INITIO | - |
dc.subject | RADICAL CYCLIZATION | - |
dc.subject | ALLYLIC CARBON | - |
dc.subject | BU3SN GROUP | - |
dc.subject | SUBSTITUTION | - |
dc.subject | CHEMISTRY | - |
dc.subject | TIN | - |
dc.title | Homolytic 1,5-transfer of chiral organosilicon groups from an enoxy oxygen to an alkoxy oxygen - implications for mechanism | - |
dc.type | Article | - |
dc.identifier.wosid | 000182569100033 | - |
dc.type.rims | ART | - |
dc.citation.beginningpage | 1182 | - |
dc.citation.endingpage | 1183 | - |
dc.citation.publicationname | CHEMICAL COMMUNICATIONS | - |
dc.contributor.localauthor | Kim, Sung Gak | - |
dc.contributor.nonIdAuthor | Horvat, SM | - |
dc.contributor.nonIdAuthor | Schiesser, CH | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | ATOM-TRANSFER | - |
dc.subject.keywordPlus | AB-INITIO | - |
dc.subject.keywordPlus | RADICAL CYCLIZATION | - |
dc.subject.keywordPlus | ALLYLIC CARBON | - |
dc.subject.keywordPlus | BU3SN GROUP | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | TIN | - |
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