A stereoselective synthesis of the C15C25 subunit of (+)-lasonolide A
The C-15-C-25 upper THP segment 2 of (+)-lasonolide A has been synthesized efficiently via diastereomeric differentiation, iodocyclization and Julia-Kocienski's sulfone olefination to install its quaternary chiral center, cis-2,6-disubstituted THP and trans-olefin, respectively. (C) 2003 Elsevier Ltd. All rights reserved.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 2003-09
- Language
- English
- Article Type
- Article
- Keywords
LASONOLIDE-A; STEREOCONTROLLED SYNTHESIS; ASYMMETRIC-SYNTHESIS; OLEFIN FORMATION; STEREOCHEMISTRY; SULFONES; SEGMENT
- Citation
TETRAHEDRON LETTERS, v.44, no.36, pp.6817 - 6819
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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