The critical amount of nitrogen on the formation of nitrogen gas pores during solidification of 25Cr-7Ni duplex stainless steels

Abstract

The effects of casting thickness, nitrogen contents, cooling rate, and Mn contents on the formation of nitrogen gas pores during solidification of 25Cr-7Ni-1.5Mo-3W duplex stainless steels (DSS) were quantitatively investigated. In the case of a sand mold, the formation of nitrogen gas pore was not affected by the thickness of castings, which ranged from 13 to 52 mm, and the critical initial nitrogen content for the formation of gas pore was 0.30 wt pct. In the case of the molds made of a stainless steel (STS) and water-cooled Cu, the critical initial nitrogen content did not change much compared to the sand mold. The amount of nitrogen gas pores increased with initial nitrogen contents of castings. The segregation of nitrogen and alloying elements was calculated with Thermo-Calc. The calculated data and the experimental results were compared to estimate the critical nitrogen partial pressure in the residual melt for the nucleation of gas pores. The effect of Mn content on the formation of gas pores was also investigated. The increase of Mn content from 1 wt pct to 2.6 wt pct changed the critical initial nitrogen content 0.30 wt pct to 0.40 wt pct.