DC Field | Value | Language |
---|---|---|
dc.contributor.author | Joo, SW | ko |
dc.contributor.author | Han, Sang Woo | ko |
dc.contributor.author | Kim, K | ko |
dc.date.accessioned | 2013-03-02T20:51:45Z | - |
dc.date.available | 2013-03-02T20:51:45Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2000-06 | - |
dc.identifier.citation | LANGMUIR, v.16, no.12, pp.5391 - 5396 | - |
dc.identifier.issn | 0743-7463 | - |
dc.identifier.uri | http://hdl.handle.net/10203/75467 | - |
dc.description.abstract | Invoking the fact that surface-enhanced Raman scattering (SERS) is a very sensitive surface-probing technique and that 1,2-ethanedithiol(1,2-EDT) is the simplest alkanedithiol molecule, we have analyzed the SER spectra of 1,2-EDT in aqueous gold sol to confirm spectroscopically the feasibility of multilayered film formation for alkanedithiols on the gold surface. We could clearly identify the S-S stretching band that reveals the formation of multilayers of 1,2-EDT on the colloidal gold surface. Surprisingly, the intermolecular disulfide bond appeared to form even at a submonolayer coverage limit, implying that the adsorption of alkanedithiol on gold does not take place homogeneously from the early stage of self-assembly. A separate ellipsometry measurement performed with vacuum-evaporated gold substrates revealed that up to tetralayers could be assembled on gold by 1,2-EDT in n-hexane while a bilayer formed in ethanol. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Multilayer formation of 1,2-ethanedithiol on gold: Surface-enhanced Raman scattering and ellipsometry study | - |
dc.type | Article | - |
dc.identifier.wosid | 000087510500027 | - |
dc.identifier.scopusid | 2-s2.0-0033687181 | - |
dc.type.rims | ART | - |
dc.citation.volume | 16 | - |
dc.citation.issue | 12 | - |
dc.citation.beginningpage | 5391 | - |
dc.citation.endingpage | 5396 | - |
dc.citation.publicationname | LANGMUIR | - |
dc.identifier.doi | 10.1021/la991331w | - |
dc.contributor.localauthor | Han, Sang Woo | - |
dc.contributor.nonIdAuthor | Joo, SW | - |
dc.contributor.nonIdAuthor | Kim, K | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | SELF-ASSEMBLED MONOLAYERS | - |
dc.subject.keywordPlus | SILVER SURFACE | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | AU(111) | - |
dc.subject.keywordPlus | THIOLS | - |
dc.subject.keywordPlus | AU | - |
dc.subject.keywordPlus | FILMS | - |
dc.subject.keywordPlus | AG | - |
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