HIGHLY STEREOSELECTIVE ALLYLATION TO CHIRAL ALPHA-KETO AMIDES DERIVED FROM (S)-INDOLINE-2-CARBOXYLIC ACID - ASYMMETRIC-SYNTHESIS OF FUNCTIONALIZED TERTIARY HOMOALLYL ALCOHOLS
The diastereoselective addition of allylsilane and - stannane in the presence of Lewis acids to new chiral alpha-keto amides derived from (S)-indoline-2-carboxylic acid resulted in optically active tertiary homoallyl alcohols with extremely high diastereoselectivities (up to dr greater than or equal to 99:1).
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 1995-09
- Language
- English
- Article Type
- Article
- Keywords
DIASTEREOSELECTIVE ADDITION; ORGANOMETALLICS; ESTERS
- Citation
TETRAHEDRON LETTERS, v.36, no.38, pp.6895 - 6898
- ISSN
- 0040-4039
- Appears in Collection
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