DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, OH | ko |
dc.contributor.author | Eo, YJ | ko |
dc.contributor.author | Choi, YK | ko |
dc.contributor.author | Bae, Byeong-Soo | ko |
dc.date.accessioned | 2013-02-27T20:58:45Z | - |
dc.date.available | 2013-02-27T20:58:45Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1999-11 | - |
dc.identifier.citation | JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, v.16, no.3, pp.235 - 241 | - |
dc.identifier.issn | 0928-0707 | - |
dc.identifier.uri | http://hdl.handle.net/10203/70806 | - |
dc.description.abstract | Structural evolution and optical properties of the silica-poly(ethylene oxide) hybrid films prepared from gamma-glycidoxypropyltrimethoxysilane (GPTS) and 1-methylimidazol (MI) are studied. Polymerization of the epoxy groups is achieved by using 1-methylimidazol as a thermal curing agent. In liquid state H-1 & C-13 NMR spectroscopy, it is found that silica condensation mainly occurs without epoxy ring opening. The epoxide polymerization is confirmed by using FT-IR, solid state CP-MAS C-13-NMR, and differential scanning calorimetry (DSC). The hybrid material is densified due to the epoxide polymerization as well as silica condensation with thermal curing. As a result, the thermal curing increases refractive index and extinction coefficient and shifts UV optical absorption edge to longer wavelength. | - |
dc.language | English | - |
dc.publisher | KLUWER ACADEMIC PUBL | - |
dc.subject | SOL-GEL PROCESS | - |
dc.subject | ALKOXIDES | - |
dc.subject | CHEMISTRY | - |
dc.title | Preparation and optical properties of silica-poly(ethylene oxide) hybrid materials | - |
dc.type | Article | - |
dc.identifier.wosid | 000082592100005 | - |
dc.identifier.scopusid | 2-s2.0-0033310591 | - |
dc.type.rims | ART | - |
dc.citation.volume | 16 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 235 | - |
dc.citation.endingpage | 241 | - |
dc.citation.publicationname | JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | - |
dc.contributor.localauthor | Bae, Byeong-Soo | - |
dc.contributor.nonIdAuthor | Park, OH | - |
dc.contributor.nonIdAuthor | Eo, YJ | - |
dc.contributor.nonIdAuthor | Choi, YK | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | sol-gel | - |
dc.subject.keywordAuthor | silica-poly(ethylene oxide) hybrid material | - |
dc.subject.keywordAuthor | epoxide polymerization | - |
dc.subject.keywordAuthor | optical properties | - |
dc.subject.keywordPlus | SOL-GEL PROCESS | - |
dc.subject.keywordPlus | ALKOXIDES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
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