ELECTROCHEMICAL-BEHAVIOR OF DODECYLBENZENESULFONIC ACID-DOPED POLYANILINE IN ORGANIC ELECTROLYTE SOLUTION

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Electrochemical properties of dodecylbenzenesulfonic acid-doped polyaniline film (PAn-DBSA) were investigated by cyclic voltammetry in an organic mixture solution of propylene carbonate-1,2-dimethoxyethane containing 1 M LiClO4. The PAn-DBSA film showed reversibility and electrochemical stability over 500 cycles in the redox process. Its electrochemical stability was explained by the ionic replacement of DBSA anions with ClO4- anions and by the deprotonation during the redox process. This behavior was confirmed from the results obtained using cyclic voltammetry and energy-dispersive X-ray spectroscopy (EDXS).
Publisher
ELSEVIER SCIENCE SA
Issue Date
1995-02
Language
English
Article Type
Article
Keywords

ELECTROACTIVE POLYANILINE; POLYMERIZATION; POLYPYRROLE; POLYMERS; MEDIA

Citation

SYNTHETIC METALS, v.68, no.3, pp.233 - 237

ISSN
0379-6779
URI
http://hdl.handle.net/10203/70559
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