Total synthesis of (+)-furanomycin
A highly enantioselective total synthesis of (+)-furanomycin 24 has been achieved via the mercury cation-mediated cyclizations of gamma-hydroxy alkene 4 and homoallylic trichloroacetimidate 11 to install the trans-2,5-disubstituted tetrahydrofuran and the (alpha S)-amino acid side chain, respectively.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 1998-04
- Language
- English
- Article Type
- Article
- Keywords
(+)-POLYOXAMIC ACID; ALLYLIC ALCOHOLS; FURANOMYCIN; REARRANGEMENT; BIOSYNTHESIS; MECHANISM; REAGENTS; ROUTES
- Citation
CHEMICAL COMMUNICATIONS, no.7, pp.761 - 762
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
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