Photoreaction of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne with methanol or acetone
Irradiation of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne (2) in methanol yields two 1:1 photoaddition products (3 and 4) via silacyclopropene intermediate. Photolysis of (2) with acetone in deaerated methylene chloride yields site specific and regioselective 1:1 adducts (7 and 8) via silacyclopropene and 1-sila-1,2-propadiene intermediate, respectively.
- Publisher
- KOREAN CHEMICAL SOC
- Issue Date
- 1998-06
- Language
- English
- Article Type
- Article
- Keywords
PHOTOCHEMISTRY; ORGANOPOLYSILANES; PHOTOLYSIS; 1-ARYL-4-(PENTAMETHYLDISILANYL)BUTA-1,3-DIYNES; PHENYLETHYNYLDISILANES; SILACYCLOPROPENES; BEHAVIOR
- Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.19, no.6, pp.686 - 689
- ISSN
- 0253-2964
- Appears in Collection
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