A study on the capacity loss with cycling in Li/LixMn2O4 cell

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The capacity loss behavior of LiMn2O4 prepared by emulsion drying method was investigated by cycling experiments giving various cutoff discharge voltages. The discharge capacity loss was also quantified depending on the cutoff discharge voltages. LiMn2O4 cathode showed most capacity loss in the high-voltage region in the 4 V range and no capacity loss in the voltage-drop region. Therefore, it could be concluded that the cubic-to-tetragonal phase change caused by the Jahn-Teller distortion is not the main cause of the capacity loss in the 4 V range. (C) 1999 Elsevier Science B.V. All rights reserved.
Publisher
ELSEVIER SCIENCE BV
Issue Date
1999-05
Language
English
Article Type
Article
Keywords

LITHIUM BATTERIES; SPINEL; TEMPERATURE; CATHODE; OXIDES; SYSTEM

Citation

MATERIALS LETTERS, v.39, no.3, pp.133 - 137

ISSN
0167-577X
DOI
10.1016/S0167-577X(98)00229-8
URI
http://hdl.handle.net/10203/69256
Appears in Collection
MS-Journal Papers(저널논문)
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