A numerical analysis was carried out in order to investigate the combustion and heat transfer characteristics in a liquid rocket engine in terms of non-gray thermal radiation and soot formation. Governing gas and droplet phase equations with PSIC model, turbulent combustion model with liquid kerosene fuel, soot formation, and non-gray thermal radiative equations are introduced. A radiation model was implemented in a compressible flow solver in order to investigate the effects of thermal radiation. The finite-volume method (FVM) was employed to solve the radiative transfer equation, and the weighted-sum-of-gray-gases model (WSGGM) was applied to model the radiation effect by a mixture of non-gray gases and gray soot particulates. After confirming the two-phase combustion behavior with soot distribution, the effects of the O/F ratio, wall temperature, and wall emissivity on the wall heat flux were investigated. It was found that the effects of soot formation and radiation are significant; as the O/F ratio increases, the wall temperature decreases. In addition, as the wall emissivity increases, the radiative heat flux on the wall increases. (c) 2006 Elsevier Ltd. All rights reserved.